Describe the term D- and L-configuration used for amino acids with examples.
The sugars are divided into two families: the D-family and L-family which have definite configurations. These configurations are represented with respect to glyceraldehyde as the standard. The glyceraldehydes may be presented by two forms as:
D-(+)-Glyceraldehyde L-(-)-Glyceraldehyde The D-configuration has -OH attached to the carbon adjacent to -CH2OH on right while L-configuration has -OH attached to the carbon adjacent to -CH2OH on left. The sugars are called D- or L-depending upon whether the configuration of the molecule is related to D-glyceraldehyde or L-glyceraldehyde. It has been found that all naturally occurring sugars belong to D-series, e.g., D-glucose D-ribose and D-fructose.
The letters ' D ' or ' L' before the name of a stereoisomer of a compound indicate the correlation of configuration of that particular stereoisomer.
This refers to their relation with one of the isomers of glyceraldehydes. Predict whether the following compound has ‘D' or ‘L' configuration.
Which monosaccharide units are present in starch, cellulose and glycogen and which linkages link these units?
Which of the following terms are correct about enzyme?
(a) Proteins (b) Dinucleotides
(c) Nucleic acids (d) Biocatalysts
Assertion (A): Vitamin D can be stored in our body.
Reason (R): Vitamin D is fat soluble vitamin.
When RNA is hydrolysed, there is no relationship among the quantities of different bases obtained. What does this fact suggest about the structure of RNA?
Assertion (A): Deoxyribose, C5H10O4 is not a carbohydrate.
Reason (R): Carbohydrates are hydrates of carbon so compounds which follow Cx(H2O)y formula are carbohydrates.
Sucrose is dextrorotatory but the mixture obtained after hydrolysis is laevorotatory. Explain.
Carbohydrates are classified on the basis of their behaviour on hydrolysis and also as reducing or non-reducing sugar. Sucrose is a .
(a) monosaccharide (b) disaccharide
(c) reducing sugar (d) non-reducing sugar
Match the vitamins given in Column I with the deficiency disease they cause given in Column II.
How do you explain the presence of all six carbon atoms in glucose in a straight chain?
α-Helix is a secondary structure of proteins formed by twisting of polypeptide chain into right handed screw like structures. Which type of interactions are responsible for making the a-helix structure stable?
Assertion (A): All naturally occurring a-amino acids except glycine are optically active.
Reason (R): Most naturally occurring amino acids have L-configuration.
Aldopentoses named ribose and 2-deoxyribose are found in nucleic acids.
What is their relative configuration?
Match the following enzyme given in Column I with the reactions they catalyse given in Column II.
Three structures are given below in which two glucose units are linked. Which of these linkages between glucose units are between C1 and C4 and which linkages are between C1 and C6?
Monosaccharides contain carbonyl group hence are classified, as aldose or ketose. The number of carbon atoms present in the monosaccharide molecule are also considered for classification. In which class of monosaccharide will you place fructose?
Assertion (A): Glycine must’be taken through diet.
Reason (R): It is an essential amino acid.
Which of the following monosaccharides are present as five membered cyclic structure (foranose structure)?
(a) Ribose (b) Glucose (c) Fructose (d) Galactose
Some enzymes are named after the reaction, where they are used. What name is given to the class of enzymes which catalyse the oxidation of one substrate with simultaneous reduction of another substrate?
Structures of glycine and alanine are given below. Show the peptide linkage in glycylalanine.
Activation energy for the acid catalysed hydrolysis of sucrose is 6.22 kJ mol-1, while hydrolysis is catalysed by the enzyme sucrase. Explain.
In fibrous proteins, polypeptide chains are held together by
(a) van der Waals forces (b) disulphide linkage
(c) electrostatic forces of attraction (d) hydrogen bonds
Assertion (A): β-glycosidic linkage is present in maltose.
Reason (R): Maltose is composed of two glucose units in which C-l of one glucose unit is linked to C-4 of another glucose unit.
Carbohydrates are essential for life in both plants and animals. Name the carbohydrates that are used as storage molecules in plants and animals, also name the carbohydrate which is present in wood or in the fibre of cotton cloth.
