Amino acids behave like salts rather than simple amines or carboxylic acids. Explain.
In aqueous solution, the -COOH group of an amino acid loses a proton and -NH2 group accepts a proton to form zwitter ion (salt).
The letters ' D ' or ' L' before the name of a stereoisomer of a compound indicate the correlation of configuration of that particular stereoisomer.
This refers to their relation with one of the isomers of glyceraldehydes. Predict whether the following compound has ‘D' or ‘L' configuration.
Match the following enzyme given in Column I with the reactions they catalyse given in Column II.
In nucleoside a base is attached at 1′ position of sugar moiety. Nucleotide is formed by linking of phosphoric acid unit to the sugar unit of nucleoside. At which position of sugar unit is the phosphoric acid linked in a nucleoside to give a nucleotide?
In fibrous proteins, polypeptide chains are held together by
(a) van der Waals forces (b) disulphide linkage
(c) electrostatic forces of attraction (d) hydrogen bonds
Aldopentoses named ribose and 2-deoxyribose are found in nucleic acids.
What is their relative configuration?
Activation energy for the acid catalysed hydrolysis of sucrose is 6.22 kJ mol-1, while hydrolysis is catalysed by the enzyme sucrase. Explain.
Which monosaccharide units are present in starch, cellulose and glycogen and which linkages link these units?
Carbohydrates are classified on the basis of their behaviour on hydrolysis and also as reducing or non-reducing sugar. Sucrose is a .
(a) monosaccharide (b) disaccharide
(c) reducing sugar (d) non-reducing sugar
Name the sugar present in milk. How many monosaccharide units are present in it? What are such oligosaccharides called?
Assertion (A): Glycine must’be taken through diet.
Reason (R): It is an essential amino acid.
Assertion (A): β-glycosidic linkage is present in maltose.
Reason (R): Maltose is composed of two glucose units in which C-l of one glucose unit is linked to C-4 of another glucose unit.
α-Helix is a secondary structure of proteins formed by twisting of polypeptide chain into right handed screw like structures. Which type of interactions are responsible for making the a-helix structure stable?
Classify the following into monosaccharides and disaccharides. Ribose, 2-deoxyribose, maltose, galactose, fructose and lactose.
Carbohydrates are essential for life in both plants and animals. Name the carbohydrates that are used as storage molecules in plants and animals, also name the carbohydrate which is present in wood or in the fibre of cotton cloth.
Some enzymes are named after the reaction, where they are used. What name is given to the class of enzymes which catalyse the oxidation of one substrate with simultaneous reduction of another substrate?
Assertion (A): Deoxyribose, C5H10O4 is not a carbohydrate.
Reason (R): Carbohydrates are hydrates of carbon so compounds which follow Cx(H2O)y formula are carbohydrates.
The melting points and solubility of amino acids in water are generally higher than those of corresponding haloacids. Explain.
Optical rotations of some compounds along with their structures are given below which of them have D configuration.
Write the reactions of D-glucose which cannot be explained by its open-chain structure. How can cyclic structure of glucose explain these reactions?
Coagulation of egg white on boiling is an example of denaturation of protein. Explain it in terms of structural changes.
Protein found in a biological system with a unique three dimensional structure and biological activity is called a native protein. When a protein in its native form, is subjected to a physical change like change in temperature or a chemical change like, change in pH, denaturation of protein takes place. Explain the cause.
When RNA is hydrolysed, there is no relationship among the quantities of different bases obtained. What does this fact suggest about the structure of RNA?
Which of the following carbohydrates are branched polymer of glucose?
(a) Amylose (b) Amylopectin (c) Cellulose (d) Glycogen
Monosaccharides contain carbonyl group hence are classified, as aldose or ketose. The number of carbon atoms present in the monosaccharide molecule are also considered for classification. In which class of monosaccharide will you place fructose?
Glucose or sucrose are soluble in water but cyclohexane and benzene (simple six membred ring compounds) are insoluble in water Explain.
Three structures are given below in which two glucose units are linked. Which of these linkages between glucose units are between C1 and C4 and which linkages are between C1 and C6?
Amino acids are classified as acidic, basis or neutral depending upon the relative number of amino and carboxyl groups in their molecule. Which of the following are acidic?