Activation energy for the acid catalysed hydrolysis of sucrose is 6.22 kJ mol-1, while hydrolysis is catalysed by the enzyme sucrase. Explain.
Enzymes are biocatalysts. They reduce the magnitude of activation energy by providing alternative path. In the hydrolysis of sucrose, the enzyme sucrase reduces the activation energy from 6.22 kJ mol-1 to 2.15 kJ mol-1. As a result, enzyme catalysed reactions occur at a much faster rate than the ordinary chemicdl reactions using conventional catalysts.
The letters ' D ' or ' L' before the name of a stereoisomer of a compound indicate the correlation of configuration of that particular stereoisomer.
This refers to their relation with one of the isomers of glyceraldehydes. Predict whether the following compound has ‘D' or ‘L' configuration.
Which monosaccharide units are present in starch, cellulose and glycogen and which linkages link these units?
When RNA is hydrolysed, there is no relationship among the quantities of different bases obtained. What does this fact suggest about the structure of RNA?
Which of the following terms are correct about enzyme?
(a) Proteins (b) Dinucleotides
(c) Nucleic acids (d) Biocatalysts
Assertion (A): Deoxyribose, C5H10O4 is not a carbohydrate.
Reason (R): Carbohydrates are hydrates of carbon so compounds which follow Cx(H2O)y formula are carbohydrates.
Carbohydrates are classified on the basis of their behaviour on hydrolysis and also as reducing or non-reducing sugar. Sucrose is a .
(a) monosaccharide (b) disaccharide
(c) reducing sugar (d) non-reducing sugar
Aldopentoses named ribose and 2-deoxyribose are found in nucleic acids.
What is their relative configuration?
Assertion (A): Vitamin D can be stored in our body.
Reason (R): Vitamin D is fat soluble vitamin.
How do you explain the presence of all six carbon atoms in glucose in a straight chain?
Sucrose is dextrorotatory but the mixture obtained after hydrolysis is laevorotatory. Explain.
Assertion (A): All naturally occurring a-amino acids except glycine are optically active.
Reason (R): Most naturally occurring amino acids have L-configuration.
Three structures are given below in which two glucose units are linked. Which of these linkages between glucose units are between C1 and C4 and which linkages are between C1 and C6?
Which of the following carbohydrates are branched polymer of glucose?
(a) Amylose (b) Amylopectin (c) Cellulose (d) Glycogen
Match the vitamins given in Column I with the deficiency disease they cause given in Column II.
Which of the following monosaccharides are present as five membered cyclic structure (foranose structure)?
(a) Ribose (b) Glucose (c) Fructose (d) Galactose
α-Helix is a secondary structure of proteins formed by twisting of polypeptide chain into right handed screw like structures. Which type of interactions are responsible for making the a-helix structure stable?
Activation energy for the acid catalysed hydrolysis of sucrose is 6.22 kJ mol-1, while hydrolysis is catalysed by the enzyme sucrase. Explain.
Assertion (A): Glycine must’be taken through diet.
Reason (R): It is an essential amino acid.
Monosaccharides contain carbonyl group hence are classified, as aldose or ketose. The number of carbon atoms present in the monosaccharide molecule are also considered for classification. In which class of monosaccharide will you place fructose?
Some enzymes are named after the reaction, where they are used. What name is given to the class of enzymes which catalyse the oxidation of one substrate with simultaneous reduction of another substrate?
Structures of glycine and alanine are given below. Show the peptide linkage in glycylalanine.
Carbohydrates are essential for life in both plants and animals. Name the carbohydrates that are used as storage molecules in plants and animals, also name the carbohydrate which is present in wood or in the fibre of cotton cloth.
Structure of a disaccharide formed by glucose and fructose is given below. Identify anomeric carbon atoms in monosaccharide units.
