Chemistry

Biomolecules

Question:

The two strands in DNA are not identical but are complementary. Explain.

Answer:

he two strands in DNA molecule are held together by hydrogen bonds between purine base of one strand and pyrimidine base of the other and vice versa. Because of different sizes and geometries of the bases, the only possible pairing in DNA are G (guanine) and C (cytosine) through three H-bonds, (i.e.,C = G) and between A (adenine) and T (thiamine) through two H-bonds (i.e., A = T). Due to this base -pairing principle, the sequence of bases in one strand automatically fixes the sequence of bases in the other strand. Thus, the two strands are complimentary and not identical.

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Biomolecules

Q 1.

During curdling of milk, what happens to sugar present in it?

Q 2.

The letters ' D ' or ' L' before the name of a stereoisomer of a compound indicate the correlation of configuration of that particular stereoisomer.
ncert-exemplar-problems-class-12-chemistry-biomolecules-21
This refers to their relation with one of the isomers of glyceraldehydes. Predict whether the following compound has ‘D' or ‘L' configuration.

Q 3.

What are essential and non-essential amino acids? Give two examples of each type.

Q 4.

When RNA is hydrolysed, there is no relationship among the quantities of different bases obtained. What does this fact suggest about the structure of RNA?

Q 5.

Describe the term D- and L-configuration used for amino acids with examples.

Q 6.

What is glycogen? How is it different from starch?

Q 7.

Which of the following terms are correct about enzyme?
(a) Proteins (b) Dinucleotides
(c) Nucleic acids (d) Biocatalysts

Q 8.

Assertion (A): Deoxyribose, C5H10O4 is not a carbohydrate.
Reason (R): Carbohydrates are hydrates of carbon so compounds which follow Cx(H2O)y formula are carbohydrates.

Q 9.

Why are vitamin A and vitamin C essential to us? Give their important sources.

Q 10.

Aldopentoses named ribose and 2-deoxyribose are found in nucleic acids.
What is their relative configuration?

Q 11.

Assertion (A): Vitamin D can be stored in our body.
Reason (R): Vitamin D is fat soluble vitamin.

Q 12.

What are the common types of secondary structure of proteins?

Q 13.

What is the difference between a nucleoside and a nucleotide?

Q 14.

Carbohydrates are classified on the basis of their behaviour on hydrolysis and also as reducing or non-reducing sugar. Sucrose is a .
(a) monosaccharide (b) disaccharide
(c) reducing sugar (d) non-reducing sugar

Q 15.

Which monosaccharide units are present in starch, cellulose and glycogen and which linkages link these units?

Q 16.

How do enzymes help a substrate to be attacked by the reagent effectively?

Q 17.

Where does the water present in the egg go after boiling the egg?

Q 18.

How do you explain the presence of all six carbon atoms in glucose in a straight chain?

Q 19.

Name the linkage connecting monosaccharide units in polysaccharides.

Q 20.

Three structures are given below in which two glucose units are linked. Which of these linkages between glucose units are between C1 and C4 and which linkages are between C1 and C6?
ncert-exemplar-problems-class-12-chemistry-biomolecules-12

Q 21.

Under what conditions glucose is converted to gluconic and saccharic acid?

Q 22.

Why does compound (A) given below not form an oxime?
ncert-exemplar-problems-class-12-chemistry-biomolecules-26

Q 23.

Assertion (A): β-glycosidic linkage is present in maltose.
ncert-exemplar-problems-class-12-chemistry-biomolecules-39
Reason (R): Maltose is composed of two glucose units in which C-l of one glucose unit is linked to C-4 of another glucose unit.

Q 24.

What are nucleic acids ? Mention their two important functions.

Q 25.

Sucrose is dextrorotatory but the mixture obtained after hydrolysis is laevorotatory. Explain.

Q 26.

What type of bonding helps in stabilising the α-helix structure of proteins?

Q 27.

ncert-exemplar-problems-class-12-chemistry-biomolecules-15

Q 28.

Some enzymes are named after the reaction, where they are used. What name is given to the class of enzymes which catalyse the oxidation of one substrate with simultaneous reduction of another substrate?

Q 29.

Amino acids behave like salts rather than simple amines or carboxylic acids. Explain.

Q 30.

Activation energy for the acid catalysed hydrolysis of sucrose is 6.22 kJ mol-1, while hydrolysis is catalysed by the enzyme sucrase. Explain.

Q 31.

What are glycosidic linkages? In which type of biomolecules are they present?

Q 32.

Assertion (A): All naturally occurring a-amino acids except glycine are optically active.
Reason (R): Most naturally occurring amino acids have L-configuration.

Q 33.

What are the expected products of hydrolysis of lactose?

Q 34.

What are monosaccharides ?

Q 35.

Write two main functions of carbohydrates in plants.

Q 36.

What is the effect of denaturation on the structure of proteins?

Q 37.

How are vitamins classified? Name the vitamin responsible for the coagulation of blood.

Q 38.

ncert-exemplar-problems-class-12-chemistry-biomolecules-23

Q 39.

Match the vitamins given in Column I with the deficiency disease they cause given in Column II.
ncert-exemplar-problems-class-12-chemistry-biomolecules-37

Q 40.

Carbohydrates are essential for life in both plants and animals. Name the carbohydrates that are used as storage molecules in plants and animals, also name the carbohydrate which is present in wood or in the fibre of cotton cloth.

Q 41.

What are the hydrolysis products of (i) sucrose, and (ii) lactose?

Q 42.

How do you explain the amphoteric behaviour of amino acids?

Q 43.

What are enzymes?

Q 44.

In disaccharides, if the reducing groups of monosaccharides, i.e., aldehydic or ketonic groups are bonded, these are non-reducing sugars. Which of the following disaccharide is a non-reducing sugar?
ncert-exemplar-problems-class-12-chemistry-biomolecules-5

Q 45.

Which of the following are purine bases?
(a) Guanine (b) Adenine (c) Thymine (d) Uracil

Q 46.

Protein found in a biological system with a unique three dimensional structure and biological activity is called a native protein. When a protein in its native form, is subjected to a physical change like change in temperature or a chemical change like, change in pH, denaturation of protein takes place. Explain the cause.

Q 47.

Why cannot Vitamin C be stored in our body?

Q 48.

Classify the following into monosaccharides and disaccharides. Ribose, 2-deoxyribose, maltose, galactose, fructose and lactose.

Q 49.

Proteins can be classified into two types on the basis of their molecular shape, i.e., fibrous proteins and globular proteins. Examples of globular proteins are
(a) insulin (b) keratin (c) albumin (d) myosin

Q 50.

Which of the following carbohydrates are branched polymer of glucose?
(a) Amylose (b) Amylopectin (c) Cellulose (d) Glycogen