Chemistry

Biomolecules

Question:

Which of the following monosaccharides are present as five membered cyclic structure (foranose structure)?
(a) Ribose (b) Glucose (c) Fructose (d) Galactose

Answer:

(a, c) Ribose and fructose are presented as five membered cyclic structure (furanose structures). They have five membered ring with analogy to the compound foran.

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Biomolecules

Q 1.

What are essential and non-essential amino acids? Give two examples of each type.

Q 2.

Assertion (A): Deoxyribose, C5H10O4 is not a carbohydrate.
Reason (R): Carbohydrates are hydrates of carbon so compounds which follow Cx(H2O)y formula are carbohydrates.

Q 3.

Aldopentoses named ribose and 2-deoxyribose are found in nucleic acids.
What is their relative configuration?

Q 4.

Three structures are given below in which two glucose units are linked. Which of these linkages between glucose units are between C1 and C4 and which linkages are between C1 and C6?
ncert-exemplar-problems-class-12-chemistry-biomolecules-12

Q 5.

During curdling of milk, what happens to sugar present in it?

Q 6.

Describe the term D- and L-configuration used for amino acids with examples.

Q 7.

Assertion (A): Vitamin D can be stored in our body.
Reason (R): Vitamin D is fat soluble vitamin.

Q 8.

Which monosaccharide units are present in starch, cellulose and glycogen and which linkages link these units?

Q 9.

What is glycogen? How is it different from starch?

Q 10.

Why does compound (A) given below not form an oxime?
ncert-exemplar-problems-class-12-chemistry-biomolecules-26

Q 11.

What is the effect of denaturation on the structure of proteins?

Q 12.

How do you explain the presence of all six carbon atoms in glucose in a straight chain?

Q 13.

Assertion (A): β-glycosidic linkage is present in maltose.
ncert-exemplar-problems-class-12-chemistry-biomolecules-39
Reason (R): Maltose is composed of two glucose units in which C-l of one glucose unit is linked to C-4 of another glucose unit.

Q 14.

Why are vitamin A and vitamin C essential to us? Give their important sources.

Q 15.

What is the difference between a nucleoside and a nucleotide?

Q 16.

Under what conditions glucose is converted to gluconic and saccharic acid?

Q 17.

The letters ' D ' or ' L' before the name of a stereoisomer of a compound indicate the correlation of configuration of that particular stereoisomer.
ncert-exemplar-problems-class-12-chemistry-biomolecules-21
This refers to their relation with one of the isomers of glyceraldehydes. Predict whether the following compound has ‘D' or ‘L' configuration.

Q 18.

Which of the following terms are correct about enzyme?
(a) Proteins (b) Dinucleotides
(c) Nucleic acids (d) Biocatalysts

Q 19.

Assertion (A): In presence of enzyme, substrate molecule can be attacked by the reagent effectively.
Reason (R): Active sites of enzymes hold the substrate molecule in a suitable position.

Q 20.

Write two main functions of carbohydrates in plants.

Q 21.

Which of the following carbohydrates are branched polymer of glucose?
(a) Amylose (b) Amylopectin (c) Cellulose (d) Glycogen

Q 22.

ncert-exemplar-problems-class-12-chemistry-biomolecules-23

Q 23.

What type of bonding helps in stabilising the α-helix structure of proteins?

Q 24.

Name the sugar present in milk. How many monosaccharide units are present in it? What are such oligosaccharides called?

Q 25.

Where does the water present in the egg go after boiling the egg?

Q 26.

When RNA is hydrolysed, there is no relationship among the quantities of different bases obtained. What does this fact suggest about the structure of RNA?

Q 27.

What happens when D-glucose is treated with . the following reagents.
(i)HI (ii) Bromine water (iii) HNO3

Q 28.

How are vitamins classified? Name the vitamin responsible for the coagulation of blood.

Q 29.

Carbohydrates are classified on the basis of their behaviour on hydrolysis and also as reducing or non-reducing sugar. Sucrose is a .
(a) monosaccharide (b) disaccharide
(c) reducing sugar (d) non-reducing sugar

Q 30.

ncert-exemplar-problems-class-12-chemistry-biomolecules-15

Q 31.

Which of the following are purine bases?
(a) Guanine (b) Adenine (c) Thymine (d) Uracil

Q 32.

Assertion (A): All naturally occurring a-amino acids except glycine are optically active.
Reason (R): Most naturally occurring amino acids have L-configuration.

Q 33.

Sucrose is dextrorotatory but the mixture obtained after hydrolysis is laevorotatory. Explain.

Q 34.

Amino acids behave like salts rather than simple amines or carboxylic acids. Explain.

Q 35.

Write the important structural and functional differences between DNA and RNA.

Q 36.

Which of the following monosaccharides are present as five membered cyclic structure (foranose structure)?
(a) Ribose (b) Glucose (c) Fructose (d) Galactose

Q 37.

Some enzymes are named after the reaction, where they are used. What name is given to the class of enzymes which catalyse the oxidation of one substrate with simultaneous reduction of another substrate?

Q 38.

How do you explain the presence of five -OH groups in glucose molecule?

Q 39.

Protein found in a biological system with a unique three dimensional structure and biological activity is called a native protein. When a protein in its native form, is subjected to a physical change like change in temperature or a chemical change like, change in pH, denaturation of protein takes place. Explain the cause.

Q 40.

Match the following enzyme given in Column I with the reactions they catalyse given in Column II.
ncert-exemplar-problems-class-12-chemistry-biomolecules-38

Q 41.

Carbohydrates are essential for life in both plants and animals. Name the carbohydrates that are used as storage molecules in plants and animals, also name the carbohydrate which is present in wood or in the fibre of cotton cloth.

Q 42.

Classify the following into monosaccharides and disaccharides. Ribose, 2-deoxyribose, maltose, galactose, fructose and lactose.

Q 43.

What is the basic structural difference between starch and cellulose?

Q 44.

Which of the following pairs represents anomers?
ncert-exemplar-problems-class-12-chemistry-biomolecules-3
ncert-exemplar-problems-class-12-chemistry-biomolecules-4

Q 45.

In disaccharides, if the reducing groups of monosaccharides, i.e., aldehydic or ketonic groups are bonded, these are non-reducing sugars. Which of the following disaccharide is a non-reducing sugar?
ncert-exemplar-problems-class-12-chemistry-biomolecules-5

Q 46.

Three cyclic structures of monosaccharides are given below which of these are anomers.
ncert-exemplar-problems-class-12-chemistry-biomolecules-9

Q 47.

Optical rotations of some compounds along with their structures are given below which of them have D configuration.
ncert-exemplar-problems-class-12-chemistry-biomolecules-10

Q 48.

Structure of a disaccharide formed by glucose and fructose is given below. Identify anomeric carbon atoms in monosaccharide units.
ncert-exemplar-problems-class-12-chemistry-biomolecules-11

Q 49.

In fibrous proteins, polypeptide chains are held together by
(a) van der Waals forces (b) disulphide linkage
(c) electrostatic forces of attraction (d) hydrogen bonds

Q 50.

Monosaccharides contain carbonyl group hence are classified, as aldose or ketose. The number of carbon atoms present in the monosaccharide molecule are also considered for classification. In which class of monosaccharide will you place fructose?