Chemistry

Biomolecules

Question:

Amino acids are classified as acidic, basis or neutral depending upon the relative number of amino and carboxyl groups in their molecule. Which of the following are acidic?
ncert-exemplar-problems-class-12-chemistry-biomolecules-13

Answer:

(b, d) Amino acids with more than one -COOH group one against – NH2 group are acidic in nature.
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Biomolecules

Q 1.

The letters ' D ' or ' L' before the name of a stereoisomer of a compound indicate the correlation of configuration of that particular stereoisomer.
ncert-exemplar-problems-class-12-chemistry-biomolecules-21
This refers to their relation with one of the isomers of glyceraldehydes. Predict whether the following compound has ‘D' or ‘L' configuration.

Q 2.

Which monosaccharide units are present in starch, cellulose and glycogen and which linkages link these units?

Q 4.

Name the linkage connecting monosaccharide units in polysaccharides.

Q 5.

Assertion (A): All naturally occurring a-amino acids except glycine are optically active.
Reason (R): Most naturally occurring amino acids have L-configuration.

Q 6.

How do enzymes help a substrate to be attacked by the reagent effectively?

Q 7.

Which sugar in called invert sugar? Why is it called so?

Q 8.

Some enzymes are named after the reaction, where they are used. What name is given to the class of enzymes which catalyse the oxidation of one substrate with simultaneous reduction of another substrate?

Q 9.

Assertion (A): Glycine must’be taken through diet.
Reason (R): It is an essential amino acid.

Q 10.

Which of the following pairs represents anomers?
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Q 11.

During curdling of milk, what happens to sugar present in it?

Q 12.

Why does compound (A) given below not form an oxime?
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Q 13.

Describe the term D- and L-configuration used for amino acids with examples.

Q 14.

Assertion (A): Vitamin D can be stored in our body.
Reason (R): Vitamin D is fat soluble vitamin.

Q 15.

What are the common types of secondary structure of proteins?

Q 16.

Under what conditions glucose is converted to gluconic and saccharic acid?

Q 17.

Monosaccharides contain carbonyl group hence are classified, as aldose or ketose. The number of carbon atoms present in the monosaccharide molecule are also considered for classification. In which class of monosaccharide will you place fructose?  

Q 18.

α-Helix is a secondary structure of proteins formed by twisting of polypeptide chain into right handed screw like structures. Which type of interactions are responsible for making the a-helix structure stable?

Q 19.

What products would be formed when a nucleotide from DNA containing thymine is hydrolysed?

Q 20.

What is glycogen? How is it different from starch?

Q 21.

How are vitamins classified? Name the vitamin responsible for the coagulation of blood.

Q 22.

Aldopentoses named ribose and 2-deoxyribose are found in nucleic acids.
What is their relative configuration?

Q 23.

Differentiate between globular and fibrous proteins.

Q 24.

Amino acids are classified as acidic, basis or neutral depending upon the relative number of amino and carboxyl groups in their molecule. Which of the following are acidic?
ncert-exemplar-problems-class-12-chemistry-biomolecules-13

Q 25.

Why cannot Vitamin C be stored in our body?

Q 26.

Carbohydrates are classified on the basis of their behaviour on hydrolysis and also as reducing or non-reducing sugar. Sucrose is a .
(a) monosaccharide (b) disaccharide
(c) reducing sugar (d) non-reducing sugar

Q 27.

Which of the following carbohydrates are branched polymer of glucose?
(a) Amylose (b) Amylopectin (c) Cellulose (d) Glycogen

Q 28.

The melting points and solubility of amino acids in water are generally higher than those of corresponding haloacids. Explain.

Q 29.

What are monosaccharides ?

Q 30.

What is the basic structural difference between starch and cellulose?

Q 31.

What are nucleic acids ? Mention their two important functions.

Q 32.

Write the important structural and functional differences between DNA and RNA.

Q 33.

Optical rotations of some compounds along with their structures are given below which of them have D configuration.
ncert-exemplar-problems-class-12-chemistry-biomolecules-10

Q 34.

Which of the following monosaccharides are present as five membered cyclic structure (foranose structure)?
(a) Ribose (b) Glucose (c) Fructose (d) Galactose

Q 35.

In nucleoside a base is attached at 1′ position of sugar moiety. Nucleotide is formed by linking of phosphoric acid unit to the sugar unit of nucleoside. At which position of sugar unit is the phosphoric acid linked in a nucleoside to give a nucleotide?

Q 36.

Protein found in a biological system with a unique three dimensional structure and biological activity is called a native protein. When a protein in its native form, is subjected to a physical change like change in temperature or a chemical change like, change in pH, denaturation of protein takes place. Explain the cause.

Q 37.

Match the vitamins given in Column I with the deficiency disease they cause given in Column II.
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Q 38.

Assertion (A): β-glycosidic linkage is present in maltose.
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Reason (R): Maltose is composed of two glucose units in which C-l of one glucose unit is linked to C-4 of another glucose unit.

Q 39.

Carbohydrates are essential for life in both plants and animals. Name the carbohydrates that are used as storage molecules in plants and animals, also name the carbohydrate which is present in wood or in the fibre of cotton cloth.

Q 40.

What are essential and non-essential amino acids? Give two examples of each type.

Q 41.

What are the different types of RNA found in the cell?

Q 42.

In disaccharides, if the reducing groups of monosaccharides, i.e., aldehydic or ketonic groups are bonded, these are non-reducing sugars. Which of the following disaccharide is a non-reducing sugar?
ncert-exemplar-problems-class-12-chemistry-biomolecules-5

Q 43.

In fibrous proteins, polypeptide chains are held together by
(a) van der Waals forces (b) disulphide linkage
(c) electrostatic forces of attraction (d) hydrogen bonds

Q 44.

Which of the following terms are correct about enzyme?
(a) Proteins (b) Dinucleotides
(c) Nucleic acids (d) Biocatalysts

Q 45.

Why must vitamin C be supplied regularly in diet?

Q 46.

Assertion (A): Deoxyribose, C5H10O4 is not a carbohydrate.
Reason (R): Carbohydrates are hydrates of carbon so compounds which follow Cx(H2O)y formula are carbohydrates.

Q 47.

Glucose or sucrose are soluble in water but cyclohexane and benzene (simple six membred ring compounds) are insoluble in water Explain.

Q 48.

Where does the water present in the egg go after boiling the egg?

Q 49.

When RNA is hydrolysed, there is no relationship among the quantities of different bases obtained. What does this fact suggest about the structure of RNA?

Q 50.

How do you explain the amphoteric behaviour of amino acids?