Chemistry

Biomolecules

Question:

Assertion (A): All naturally occurring a-amino acids except glycine are optically active.
Reason (R): Most naturally occurring amino acids have L-configuration.

Answer:

(e) All a-amino acids except glycine contain at least one chiral carbon.

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Biomolecules

Q 1.

The letters ' D ' or ' L' before the name of a stereoisomer of a compound indicate the correlation of configuration of that particular stereoisomer.
ncert-exemplar-problems-class-12-chemistry-biomolecules-21
This refers to their relation with one of the isomers of glyceraldehydes. Predict whether the following compound has ‘D' or ‘L' configuration.

Q 2.

During curdling of milk, what happens to sugar present in it?

Q 3.

What are essential and non-essential amino acids? Give two examples of each type.

Q 4.

Which of the following terms are correct about enzyme?
(a) Proteins (b) Dinucleotides
(c) Nucleic acids (d) Biocatalysts

Q 5.

What is glycogen? How is it different from starch?

Q 6.

Describe the term D- and L-configuration used for amino acids with examples.

Q 7.

Why are vitamin A and vitamin C essential to us? Give their important sources.

Q 8.

Name the linkage connecting monosaccharide units in polysaccharides.

Q 9.

Assertion (A): Deoxyribose, C5H10O4 is not a carbohydrate.
Reason (R): Carbohydrates are hydrates of carbon so compounds which follow Cx(H2O)y formula are carbohydrates.

Q 10.

Which monosaccharide units are present in starch, cellulose and glycogen and which linkages link these units?

Q 11.

Assertion (A): Vitamin D can be stored in our body.
Reason (R): Vitamin D is fat soluble vitamin.

Q 12.

Where does the water present in the egg go after boiling the egg?

Q 13.

When RNA is hydrolysed, there is no relationship among the quantities of different bases obtained. What does this fact suggest about the structure of RNA?

Q 14.

What is the difference between a nucleoside and a nucleotide?

Q 15.

Why must vitamin C be supplied regularly in diet?

Q 16.

What are the common types of secondary structure of proteins?

Q 17.

What type of bonding helps in stabilising the α-helix structure of proteins?

Q 18.

Differentiate between globular and fibrous proteins.

Q 19.

How do you explain the presence of all six carbon atoms in glucose in a straight chain?

Q 20.

Why does compound (A) given below not form an oxime?
ncert-exemplar-problems-class-12-chemistry-biomolecules-26

Q 21.

Activation energy for the acid catalysed hydrolysis of sucrose is 6.22 kJ mol-1, while hydrolysis is catalysed by the enzyme sucrase. Explain.

Q 22.

Match the following enzyme given in Column I with the reactions they catalyse given in Column II.
ncert-exemplar-problems-class-12-chemistry-biomolecules-38

Q 23.

What are enzymes?

Q 24.

What is the effect of denaturation on the structure of proteins?

Q 25.

The two strands in DNA are not identical but are complementary. Explain.

Q 26.

Three structures are given below in which two glucose units are linked. Which of these linkages between glucose units are between C1 and C4 and which linkages are between C1 and C6?
ncert-exemplar-problems-class-12-chemistry-biomolecules-12

Q 27.

ncert-exemplar-problems-class-12-chemistry-biomolecules-15

Q 28.

Write the important structural and functional differences between DNA and RNA.

Q 29.

Monosaccharides contain carbonyl group hence are classified, as aldose or ketose. The number of carbon atoms present in the monosaccharide molecule are also considered for classification. In which class of monosaccharide will you place fructose?  

Q 30.

ncert-exemplar-problems-class-12-chemistry-biomolecules-23

Q 31.

α-Helix is a secondary structure of proteins formed by twisting of polypeptide chain into right handed screw like structures. Which type of interactions are responsible for making the a-helix structure stable?

Q 32.

Carbohydrates are classified on the basis of their behaviour on hydrolysis and also as reducing or non-reducing sugar. Sucrose is a .
(a) monosaccharide (b) disaccharide
(c) reducing sugar (d) non-reducing sugar

Q 33.

Which of the following monosaccharides are present as five membered cyclic structure (foranose structure)?
(a) Ribose (b) Glucose (c) Fructose (d) Galactose

Q 34.

Aldopentoses named ribose and 2-deoxyribose are found in nucleic acids.
What is their relative configuration?

Q 35.

Some enzymes are named after the reaction, where they are used. What name is given to the class of enzymes which catalyse the oxidation of one substrate with simultaneous reduction of another substrate?

Q 36.

Amino acids behave like salts rather than simple amines or carboxylic acids. Explain.

Q 37.

Structures of glycine and alanine are given below. Show the peptide linkage in glycylalanine.
ncert-exemplar-problems-class-12-chemistry-biomolecules-30

Q 38.

How do enzymes help a substrate to be attacked by the reagent effectively?

Q 39.

Match the vitamins given in Column I with the deficiency disease they cause given in Column II.
ncert-exemplar-problems-class-12-chemistry-biomolecules-37

Q 40.

Classify the following into monosaccharides and disaccharides. Ribose, 2-deoxyribose, maltose, galactose, fructose and lactose.

Q 41.

Three cyclic structures of monosaccharides are given below which of these are anomers.
ncert-exemplar-problems-class-12-chemistry-biomolecules-9

Q 42.

Which of the following carbohydrates are branched polymer of glucose?
(a) Amylose (b) Amylopectin (c) Cellulose (d) Glycogen

Q 43.

Sucrose is dextrorotatory but the mixture obtained after hydrolysis is laevorotatory. Explain.

Q 44.

Assertion (A): All naturally occurring a-amino acids except glycine are optically active.
Reason (R): Most naturally occurring amino acids have L-configuration.

Q 45.

Carbohydrates are essential for life in both plants and animals. Name the carbohydrates that are used as storage molecules in plants and animals, also name the carbohydrate which is present in wood or in the fibre of cotton cloth.

Q 46.

What are the expected products of hydrolysis of lactose?

Q 47.

Why cannot Vitamin C be stored in our body?

Q 48.

What products would be formed when a nucleotide from DNA containing thymine is hydrolysed?

Q 49.

What are monosaccharides ?

Q 50.

Write two main functions of carbohydrates in plants.