Chemistry

Biomolecules

Question:

Write two main functions of carbohydrates in plants.

Answer:

Two major functions of carbohydrates in plants are following
(a)Structural material for plant cell walls: The polysaccharide cellulose acts as the chief structural material of the plant cell walls.
(b)Reserve food material: The polysaccharide starch is the major reserve food material in the plants. It is stored in seeds and act as the reserve food material for the tiny plant till it is capable of making its own food by photosynthesis.

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Biomolecules

Q 1.

What are essential and non-essential amino acids? Give two examples of each type.

Q 2.

Assertion (A): Deoxyribose, C5H10O4 is not a carbohydrate.
Reason (R): Carbohydrates are hydrates of carbon so compounds which follow Cx(H2O)y formula are carbohydrates.

Q 3.

Aldopentoses named ribose and 2-deoxyribose are found in nucleic acids.
What is their relative configuration?

Q 4.

Three structures are given below in which two glucose units are linked. Which of these linkages between glucose units are between C1 and C4 and which linkages are between C1 and C6?
ncert-exemplar-problems-class-12-chemistry-biomolecules-12

Q 5.

During curdling of milk, what happens to sugar present in it?

Q 6.

Describe the term D- and L-configuration used for amino acids with examples.

Q 7.

Assertion (A): Vitamin D can be stored in our body.
Reason (R): Vitamin D is fat soluble vitamin.

Q 8.

What is glycogen? How is it different from starch?

Q 9.

Which monosaccharide units are present in starch, cellulose and glycogen and which linkages link these units?

Q 10.

Why does compound (A) given below not form an oxime?
ncert-exemplar-problems-class-12-chemistry-biomolecules-26

Q 11.

What is the effect of denaturation on the structure of proteins?

Q 12.

How do you explain the presence of all six carbon atoms in glucose in a straight chain?

Q 13.

Assertion (A): β-glycosidic linkage is present in maltose.
ncert-exemplar-problems-class-12-chemistry-biomolecules-39
Reason (R): Maltose is composed of two glucose units in which C-l of one glucose unit is linked to C-4 of another glucose unit.

Q 14.

Why are vitamin A and vitamin C essential to us? Give their important sources.

Q 15.

What is the difference between a nucleoside and a nucleotide?

Q 16.

Under what conditions glucose is converted to gluconic and saccharic acid?

Q 17.

Assertion (A): In presence of enzyme, substrate molecule can be attacked by the reagent effectively.
Reason (R): Active sites of enzymes hold the substrate molecule in a suitable position.

Q 18.

Which of the following carbohydrates are branched polymer of glucose?
(a) Amylose (b) Amylopectin (c) Cellulose (d) Glycogen

Q 19.

Which of the following terms are correct about enzyme?
(a) Proteins (b) Dinucleotides
(c) Nucleic acids (d) Biocatalysts

Q 20.

The letters ' D ' or ' L' before the name of a stereoisomer of a compound indicate the correlation of configuration of that particular stereoisomer.
ncert-exemplar-problems-class-12-chemistry-biomolecules-21
This refers to their relation with one of the isomers of glyceraldehydes. Predict whether the following compound has ‘D' or ‘L' configuration.

Q 21.

ncert-exemplar-problems-class-12-chemistry-biomolecules-23

Q 22.

Write two main functions of carbohydrates in plants.

Q 23.

What type of bonding helps in stabilising the α-helix structure of proteins?

Q 24.

Name the sugar present in milk. How many monosaccharide units are present in it? What are such oligosaccharides called?

Q 25.

Where does the water present in the egg go after boiling the egg?

Q 26.

When RNA is hydrolysed, there is no relationship among the quantities of different bases obtained. What does this fact suggest about the structure of RNA?

Q 27.

What happens when D-glucose is treated with . the following reagents.
(i)HI (ii) Bromine water (iii) HNO3

Q 28.

Carbohydrates are classified on the basis of their behaviour on hydrolysis and also as reducing or non-reducing sugar. Sucrose is a .
(a) monosaccharide (b) disaccharide
(c) reducing sugar (d) non-reducing sugar

Q 29.

ncert-exemplar-problems-class-12-chemistry-biomolecules-15

Q 30.

Which of the following are purine bases?
(a) Guanine (b) Adenine (c) Thymine (d) Uracil

Q 31.

Assertion (A): All naturally occurring a-amino acids except glycine are optically active.
Reason (R): Most naturally occurring amino acids have L-configuration.

Q 32.

How are vitamins classified? Name the vitamin responsible for the coagulation of blood.

Q 33.

Which of the following monosaccharides are present as five membered cyclic structure (foranose structure)?
(a) Ribose (b) Glucose (c) Fructose (d) Galactose

Q 34.

Sucrose is dextrorotatory but the mixture obtained after hydrolysis is laevorotatory. Explain.

Q 35.

Amino acids behave like salts rather than simple amines or carboxylic acids. Explain.

Q 36.

Match the following enzyme given in Column I with the reactions they catalyse given in Column II.
ncert-exemplar-problems-class-12-chemistry-biomolecules-38

Q 37.

Carbohydrates are essential for life in both plants and animals. Name the carbohydrates that are used as storage molecules in plants and animals, also name the carbohydrate which is present in wood or in the fibre of cotton cloth.

Q 38.

Classify the following into monosaccharides and disaccharides. Ribose, 2-deoxyribose, maltose, galactose, fructose and lactose.

Q 39.

What is the basic structural difference between starch and cellulose?

Q 40.

Write the important structural and functional differences between DNA and RNA.

Q 41.

Which of the following pairs represents anomers?
ncert-exemplar-problems-class-12-chemistry-biomolecules-3
ncert-exemplar-problems-class-12-chemistry-biomolecules-4

Q 42.

In disaccharides, if the reducing groups of monosaccharides, i.e., aldehydic or ketonic groups are bonded, these are non-reducing sugars. Which of the following disaccharide is a non-reducing sugar?
ncert-exemplar-problems-class-12-chemistry-biomolecules-5

Q 43.

Three cyclic structures of monosaccharides are given below which of these are anomers.
ncert-exemplar-problems-class-12-chemistry-biomolecules-9

Q 44.

Optical rotations of some compounds along with their structures are given below which of them have D configuration.
ncert-exemplar-problems-class-12-chemistry-biomolecules-10

Q 45.

Structure of a disaccharide formed by glucose and fructose is given below. Identify anomeric carbon atoms in monosaccharide units.
ncert-exemplar-problems-class-12-chemistry-biomolecules-11

Q 46.

In fibrous proteins, polypeptide chains are held together by
(a) van der Waals forces (b) disulphide linkage
(c) electrostatic forces of attraction (d) hydrogen bonds

Q 47.

Monosaccharides contain carbonyl group hence are classified, as aldose or ketose. The number of carbon atoms present in the monosaccharide molecule are also considered for classification. In which class of monosaccharide will you place fructose?  

Q 48.

α-Helix is a secondary structure of proteins formed by twisting of polypeptide chain into right handed screw like structures. Which type of interactions are responsible for making the a-helix structure stable?

Q 49.

Some enzymes are named after the reaction, where they are used. What name is given to the class of enzymes which catalyse the oxidation of one substrate with simultaneous reduction of another substrate?

Q 50.

How do you explain the presence of five -OH groups in glucose molecule?