Chemistry

Biomolecules

Question:

Three structures are given below in which two glucose units are linked. Which of these linkages between glucose units are between C1 and C4 and which linkages are between C1 and C6?
ncert-exemplar-problems-class-12-chemistry-biomolecules-12

Answer:

(c) (A) and (C) are between Cl and C4, (B) is between Cl and C6.

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Biomolecules

Q 1.

The letters ' D ' or ' L' before the name of a stereoisomer of a compound indicate the correlation of configuration of that particular stereoisomer.
ncert-exemplar-problems-class-12-chemistry-biomolecules-21
This refers to their relation with one of the isomers of glyceraldehydes. Predict whether the following compound has ‘D' or ‘L' configuration.

Q 2.

Which monosaccharide units are present in starch, cellulose and glycogen and which linkages link these units?

Q 3.

Name the linkage connecting monosaccharide units in polysaccharides.

Q 5.

Assertion (A): All naturally occurring a-amino acids except glycine are optically active.
Reason (R): Most naturally occurring amino acids have L-configuration.

Q 6.

How do enzymes help a substrate to be attacked by the reagent effectively?

Q 7.

Which sugar in called invert sugar? Why is it called so?

Q 8.

Some enzymes are named after the reaction, where they are used. What name is given to the class of enzymes which catalyse the oxidation of one substrate with simultaneous reduction of another substrate?

Q 9.

Why does compound (A) given below not form an oxime?
ncert-exemplar-problems-class-12-chemistry-biomolecules-26

Q 10.

Assertion (A): Vitamin D can be stored in our body.
Reason (R): Vitamin D is fat soluble vitamin.

Q 11.

Assertion (A): Glycine must’be taken through diet.
Reason (R): It is an essential amino acid.

Q 12.

What are the common types of secondary structure of proteins?

Q 13.

Which of the following pairs represents anomers?
ncert-exemplar-problems-class-12-chemistry-biomolecules-3
ncert-exemplar-problems-class-12-chemistry-biomolecules-4

Q 14.

During curdling of milk, what happens to sugar present in it?

Q 15.

Describe the term D- and L-configuration used for amino acids with examples.

Q 16.

α-Helix is a secondary structure of proteins formed by twisting of polypeptide chain into right handed screw like structures. Which type of interactions are responsible for making the a-helix structure stable?

Q 17.

What products would be formed when a nucleotide from DNA containing thymine is hydrolysed?

Q 18.

Aldopentoses named ribose and 2-deoxyribose are found in nucleic acids.
What is their relative configuration?

Q 19.

What is glycogen? How is it different from starch?

Q 20.

Differentiate between globular and fibrous proteins.

Q 21.

How are vitamins classified? Name the vitamin responsible for the coagulation of blood.

Q 22.

Amino acids are classified as acidic, basis or neutral depending upon the relative number of amino and carboxyl groups in their molecule. Which of the following are acidic?
ncert-exemplar-problems-class-12-chemistry-biomolecules-13

Q 23.

Monosaccharides contain carbonyl group hence are classified, as aldose or ketose. The number of carbon atoms present in the monosaccharide molecule are also considered for classification. In which class of monosaccharide will you place fructose?  

Q 24.

Carbohydrates are classified on the basis of their behaviour on hydrolysis and also as reducing or non-reducing sugar. Sucrose is a .
(a) monosaccharide (b) disaccharide
(c) reducing sugar (d) non-reducing sugar

Q 25.

Which of the following carbohydrates are branched polymer of glucose?
(a) Amylose (b) Amylopectin (c) Cellulose (d) Glycogen

Q 26.

Under what conditions glucose is converted to gluconic and saccharic acid?

Q 27.

What is the basic structural difference between starch and cellulose?

Q 28.

What are nucleic acids ? Mention their two important functions.

Q 29.

Optical rotations of some compounds along with their structures are given below which of them have D configuration.
ncert-exemplar-problems-class-12-chemistry-biomolecules-10

Q 30.

Which of the following monosaccharides are present as five membered cyclic structure (foranose structure)?
(a) Ribose (b) Glucose (c) Fructose (d) Galactose

Q 31.

Protein found in a biological system with a unique three dimensional structure and biological activity is called a native protein. When a protein in its native form, is subjected to a physical change like change in temperature or a chemical change like, change in pH, denaturation of protein takes place. Explain the cause.

Q 32.

Match the vitamins given in Column I with the deficiency disease they cause given in Column II.
ncert-exemplar-problems-class-12-chemistry-biomolecules-37

Q 33.

Assertion (A): β-glycosidic linkage is present in maltose.
ncert-exemplar-problems-class-12-chemistry-biomolecules-39
Reason (R): Maltose is composed of two glucose units in which C-l of one glucose unit is linked to C-4 of another glucose unit.

Q 34.

Carbohydrates are essential for life in both plants and animals. Name the carbohydrates that are used as storage molecules in plants and animals, also name the carbohydrate which is present in wood or in the fibre of cotton cloth.

Q 35.

The melting points and solubility of amino acids in water are generally higher than those of corresponding haloacids. Explain.

Q 36.

Why cannot Vitamin C be stored in our body?

Q 37.

Write the important structural and functional differences between DNA and RNA.

Q 38.

In disaccharides, if the reducing groups of monosaccharides, i.e., aldehydic or ketonic groups are bonded, these are non-reducing sugars. Which of the following disaccharide is a non-reducing sugar?
ncert-exemplar-problems-class-12-chemistry-biomolecules-5

Q 39.

Which of the following terms are correct about enzyme?
(a) Proteins (b) Dinucleotides
(c) Nucleic acids (d) Biocatalysts

Q 40.

In nucleoside a base is attached at 1′ position of sugar moiety. Nucleotide is formed by linking of phosphoric acid unit to the sugar unit of nucleoside. At which position of sugar unit is the phosphoric acid linked in a nucleoside to give a nucleotide?

Q 41.

Why must vitamin C be supplied regularly in diet?

Q 42.

Glucose or sucrose are soluble in water but cyclohexane and benzene (simple six membred ring compounds) are insoluble in water Explain.

Q 43.

Where does the water present in the egg go after boiling the egg?

Q 44.

When RNA is hydrolysed, there is no relationship among the quantities of different bases obtained. What does this fact suggest about the structure of RNA?

Q 45.

How do you explain the amphoteric behaviour of amino acids?

Q 46.

What are the different types of RNA found in the cell?

Q 47.

In fibrous proteins, polypeptide chains are held together by
(a) van der Waals forces (b) disulphide linkage
(c) electrostatic forces of attraction (d) hydrogen bonds

Q 48.

How do you explain the presence of all six carbon atoms in glucose in a straight chain?

Q 49.

How do you explain the presence of five -OH groups in glucose molecule?

Q 50.

How do you explain the presence of an aldehydic group in a glucose molecule?