Chemistry

Biomolecules

Question:

How do you explain the amphoteric behaviour of amino acids?

Answer:

Amino acids contain an acidic (carboxyl group) and basic (amino group) group in the same molecule. In aqueous solution, they neutralize each other. The carboxyl group loses a proton while the amino group accepts it. As a result, a dipolar or zwitter ion is formed.
ncert-solutions-for-class-12-chemistry-biomolecules-10
In zwitter ionjc form, a-amino acid show amphoteric behaviour as they react with both acids and bases.
ncert-solutions-for-class-12-chemistry-biomolecules-11

previuos
next

Biomolecules

Q 1.

What are essential and non-essential amino acids? Give two examples of each type.

Q 2.

During curdling of milk, what happens to sugar present in it?

Q 3.

Three structures are given below in which two glucose units are linked. Which of these linkages between glucose units are between C1 and C4 and which linkages are between C1 and C6?
ncert-exemplar-problems-class-12-chemistry-biomolecules-12

Q 4.

Describe the term D- and L-configuration used for amino acids with examples.

Q 5.

Assertion (A): Deoxyribose, C5H10O4 is not a carbohydrate.
Reason (R): Carbohydrates are hydrates of carbon so compounds which follow Cx(H2O)y formula are carbohydrates.

Q 6.

The letters ' D ' or ' L' before the name of a stereoisomer of a compound indicate the correlation of configuration of that particular stereoisomer.
ncert-exemplar-problems-class-12-chemistry-biomolecules-21
This refers to their relation with one of the isomers of glyceraldehydes. Predict whether the following compound has ‘D' or ‘L' configuration.

Q 7.

Aldopentoses named ribose and 2-deoxyribose are found in nucleic acids.
What is their relative configuration?

Q 8.

What is glycogen? How is it different from starch?

Q 9.

When RNA is hydrolysed, there is no relationship among the quantities of different bases obtained. What does this fact suggest about the structure of RNA?

Q 10.

Assertion (A): Vitamin D can be stored in our body.
Reason (R): Vitamin D is fat soluble vitamin.

Q 11.

Which of the following terms are correct about enzyme?
(a) Proteins (b) Dinucleotides
(c) Nucleic acids (d) Biocatalysts

Q 12.

Why does compound (A) given below not form an oxime?
ncert-exemplar-problems-class-12-chemistry-biomolecules-26

Q 13.

How do you explain the presence of all six carbon atoms in glucose in a straight chain?

Q 14.

What is the difference between a nucleoside and a nucleotide?

Q 15.

Assertion (A): β-glycosidic linkage is present in maltose.
ncert-exemplar-problems-class-12-chemistry-biomolecules-39
Reason (R): Maltose is composed of two glucose units in which C-l of one glucose unit is linked to C-4 of another glucose unit.

Q 16.

Why are vitamin A and vitamin C essential to us? Give their important sources.

Q 17.

Name the linkage connecting monosaccharide units in polysaccharides.

Q 18.

Which monosaccharide units are present in starch, cellulose and glycogen and which linkages link these units?

Q 19.

How do enzymes help a substrate to be attacked by the reagent effectively?

Q 20.

Where does the water present in the egg go after boiling the egg?

Q 21.

What is the effect of denaturation on the structure of proteins?

Q 22.

ncert-exemplar-problems-class-12-chemistry-biomolecules-23

Q 23.

What are the common types of secondary structure of proteins?

Q 24.

What type of bonding helps in stabilising the α-helix structure of proteins?

Q 25.

Some enzymes are named after the reaction, where they are used. What name is given to the class of enzymes which catalyse the oxidation of one substrate with simultaneous reduction of another substrate?

Q 26.

Amino acids behave like salts rather than simple amines or carboxylic acids. Explain.

Q 27.

How are vitamins classified? Name the vitamin responsible for the coagulation of blood.

Q 28.

Carbohydrates are classified on the basis of their behaviour on hydrolysis and also as reducing or non-reducing sugar. Sucrose is a .
(a) monosaccharide (b) disaccharide
(c) reducing sugar (d) non-reducing sugar

Q 29.

Why must vitamin C be supplied regularly in diet?

Q 30.

Carbohydrates are essential for life in both plants and animals. Name the carbohydrates that are used as storage molecules in plants and animals, also name the carbohydrate which is present in wood or in the fibre of cotton cloth.

Q 31.

ncert-exemplar-problems-class-12-chemistry-biomolecules-15

Q 32.

In fibrous proteins, polypeptide chains are held together by
(a) van der Waals forces (b) disulphide linkage
(c) electrostatic forces of attraction (d) hydrogen bonds

Q 33.

Sucrose is dextrorotatory but the mixture obtained after hydrolysis is laevorotatory. Explain.

Q 34.

Match the following enzyme given in Column I with the reactions they catalyse given in Column II.
ncert-exemplar-problems-class-12-chemistry-biomolecules-38

Q 35.

The two strands in DNA are not identical but are complementary. Explain.

Q 36.

Which of the following are purine bases?
(a) Guanine (b) Adenine (c) Thymine (d) Uracil

Q 37.

Structures of glycine and alanine are given below. Show the peptide linkage in glycylalanine.
ncert-exemplar-problems-class-12-chemistry-biomolecules-30

Q 38.

Assertion (A): All naturally occurring a-amino acids except glycine are optically active.
Reason (R): Most naturally occurring amino acids have L-configuration.

Q 39.

In disaccharides, if the reducing groups of monosaccharides, i.e., aldehydic or ketonic groups are bonded, these are non-reducing sugars. Which of the following disaccharide is a non-reducing sugar?
ncert-exemplar-problems-class-12-chemistry-biomolecules-5

Q 40.

Which of the following carbohydrates are branched polymer of glucose?
(a) Amylose (b) Amylopectin (c) Cellulose (d) Glycogen

Q 41.

Under what conditions glucose is converted to gluconic and saccharic acid?

Q 42.

What are the expected products of hydrolysis of lactose?

Q 43.

How do you explain the absence of aldehyde group in the pentaacetate of D-glucose?

Q 44.

What are reducing sugars?

Q 45.

Write two main functions of carbohydrates in plants.

Q 46.

How do you explain the amphoteric behaviour of amino acids?

Q 47.

What are enzymes?

Q 48.

What are nucleic acids ? Mention their two important functions.

Q 49.

Name the sugar present in milk. How many monosaccharide units are present in it? What are such oligosaccharides called?

Q 50.

In nucleoside a base is attached at 1′ position of sugar moiety. Nucleotide is formed by linking of phosphoric acid unit to the sugar unit of nucleoside. At which position of sugar unit is the phosphoric acid linked in a nucleoside to give a nucleotide?