Chemistry

Biomolecules

Question:

What are enzymes?

Answer:

Enzymes are biological catalyst. Each biological reaction requires a different enzyme. Thus, as compared to conventional catalyst enzymes are very specific and efficient in their action. Each type of enzyme has its own specific optimum conditions of concentration, pH and temperature at which it works best.

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Biomolecules

Q 1.

What are essential and non-essential amino acids? Give two examples of each type.

Q 2.

Aldopentoses named ribose and 2-deoxyribose are found in nucleic acids.
What is their relative configuration?

Q 3.

During curdling of milk, what happens to sugar present in it?

Q 4.

Assertion (A): Deoxyribose, C5H10O4 is not a carbohydrate.
Reason (R): Carbohydrates are hydrates of carbon so compounds which follow Cx(H2O)y formula are carbohydrates.

Q 5.

Three structures are given below in which two glucose units are linked. Which of these linkages between glucose units are between C1 and C4 and which linkages are between C1 and C6?
ncert-exemplar-problems-class-12-chemistry-biomolecules-12

Q 6.

Describe the term D- and L-configuration used for amino acids with examples.

Q 7.

What is glycogen? How is it different from starch?

Q 8.

When RNA is hydrolysed, there is no relationship among the quantities of different bases obtained. What does this fact suggest about the structure of RNA?

Q 9.

How do you explain the presence of all six carbon atoms in glucose in a straight chain?

Q 10.

Which monosaccharide units are present in starch, cellulose and glycogen and which linkages link these units?

Q 11.

The letters ' D ' or ' L' before the name of a stereoisomer of a compound indicate the correlation of configuration of that particular stereoisomer.
ncert-exemplar-problems-class-12-chemistry-biomolecules-21
This refers to their relation with one of the isomers of glyceraldehydes. Predict whether the following compound has ‘D' or ‘L' configuration.

Q 12.

Assertion (A): Vitamin D can be stored in our body.
Reason (R): Vitamin D is fat soluble vitamin.

Q 13.

Why are vitamin A and vitamin C essential to us? Give their important sources.

Q 14.

Which of the following terms are correct about enzyme?
(a) Proteins (b) Dinucleotides
(c) Nucleic acids (d) Biocatalysts

Q 15.

Where does the water present in the egg go after boiling the egg?

Q 16.

What is the difference between a nucleoside and a nucleotide?

Q 17.

Why does compound (A) given below not form an oxime?
ncert-exemplar-problems-class-12-chemistry-biomolecules-26

Q 18.

Assertion (A): β-glycosidic linkage is present in maltose.
ncert-exemplar-problems-class-12-chemistry-biomolecules-39
Reason (R): Maltose is composed of two glucose units in which C-l of one glucose unit is linked to C-4 of another glucose unit.

Q 19.

What type of bonding helps in stabilising the α-helix structure of proteins?

Q 20.

What is the effect of denaturation on the structure of proteins?

Q 21.

ncert-exemplar-problems-class-12-chemistry-biomolecules-23

Q 22.

How are vitamins classified? Name the vitamin responsible for the coagulation of blood.

Q 23.

Under what conditions glucose is converted to gluconic and saccharic acid?

Q 24.

How do enzymes help a substrate to be attacked by the reagent effectively?

Q 25.

Carbohydrates are classified on the basis of their behaviour on hydrolysis and also as reducing or non-reducing sugar. Sucrose is a .
(a) monosaccharide (b) disaccharide
(c) reducing sugar (d) non-reducing sugar

Q 26.

ncert-exemplar-problems-class-12-chemistry-biomolecules-15

Q 27.

Which of the following are purine bases?
(a) Guanine (b) Adenine (c) Thymine (d) Uracil

Q 28.

Name the linkage connecting monosaccharide units in polysaccharides.

Q 29.

Sucrose is dextrorotatory but the mixture obtained after hydrolysis is laevorotatory. Explain.

Q 30.

Carbohydrates are essential for life in both plants and animals. Name the carbohydrates that are used as storage molecules in plants and animals, also name the carbohydrate which is present in wood or in the fibre of cotton cloth.

Q 31.

Which of the following carbohydrates are branched polymer of glucose?
(a) Amylose (b) Amylopectin (c) Cellulose (d) Glycogen

Q 32.

What are the expected products of hydrolysis of lactose?

Q 33.

Write two main functions of carbohydrates in plants.

Q 34.

What are the common types of secondary structure of proteins?

Q 35.

Write the important structural and functional differences between DNA and RNA.

Q 36.

In disaccharides, if the reducing groups of monosaccharides, i.e., aldehydic or ketonic groups are bonded, these are non-reducing sugars. Which of the following disaccharide is a non-reducing sugar?
ncert-exemplar-problems-class-12-chemistry-biomolecules-5

Q 37.

In fibrous proteins, polypeptide chains are held together by
(a) van der Waals forces (b) disulphide linkage
(c) electrostatic forces of attraction (d) hydrogen bonds

Q 38.

Name the sugar present in milk. How many monosaccharide units are present in it? What are such oligosaccharides called?

Q 39.

Some enzymes are named after the reaction, where they are used. What name is given to the class of enzymes which catalyse the oxidation of one substrate with simultaneous reduction of another substrate?

Q 40.

Structures of glycine and alanine are given below. Show the peptide linkage in glycylalanine.
ncert-exemplar-problems-class-12-chemistry-biomolecules-30

Q 41.

Assertion (A): All naturally occurring a-amino acids except glycine are optically active.
Reason (R): Most naturally occurring amino acids have L-configuration.

Q 42.

Assertion (A): In presence of enzyme, substrate molecule can be attacked by the reagent effectively.
Reason (R): Active sites of enzymes hold the substrate molecule in a suitable position.

Q 43.

What do you understand by the term glycosidic linkage?

Q 44.

Amino acids behave like salts rather than simple amines or carboxylic acids. Explain.

Q 45.

How do you explain the presence of an aldehydic group in a glucose molecule?

Q 46.

What is the basic structural difference between starch and cellulose?

Q 47.

What happens when D-glucose is treated with . the following reagents.
(i)HI (ii) Bromine water (iii) HNO3

Q 48.

How do you explain the amphoteric behaviour of amino acids?

Q 49.

What are enzymes?

Q 50.

Which of the following pairs represents anomers?
ncert-exemplar-problems-class-12-chemistry-biomolecules-3
ncert-exemplar-problems-class-12-chemistry-biomolecules-4