The melting points and solubility of amino acids in water are generally higher than those of corresponding haloacids. Explain.
The amino acids exist as zwitter ions, H3N+ — CHR-COO-. Due to this dipolar salt like character, they have strong dipole-dipole attractions. Therefore, their melting points are higher than corresponding haloacids which do not have salt like character.
Due to salt like character, amino acids intereact strongly with water. As a result, their solubility in water is higher than corresponding haloacids which do not have salt like character.
Aldopentoses named ribose and 2-deoxyribose are found in nucleic acids.
What is their relative configuration?
Assertion (A): Deoxyribose, C5H10O4 is not a carbohydrate.
Reason (R): Carbohydrates are hydrates of carbon so compounds which follow Cx(H2O)y formula are carbohydrates.
Three structures are given below in which two glucose units are linked. Which of these linkages between glucose units are between C1 and C4 and which linkages are between C1 and C6?
When RNA is hydrolysed, there is no relationship among the quantities of different bases obtained. What does this fact suggest about the structure of RNA?
Which monosaccharide units are present in starch, cellulose and glycogen and which linkages link these units?
The letters ' D ' or ' L' before the name of a stereoisomer of a compound indicate the correlation of configuration of that particular stereoisomer.
This refers to their relation with one of the isomers of glyceraldehydes. Predict whether the following compound has ‘D' or ‘L' configuration.
Assertion (A): Vitamin D can be stored in our body.
Reason (R): Vitamin D is fat soluble vitamin.
Which of the following terms are correct about enzyme?
(a) Proteins (b) Dinucleotides
(c) Nucleic acids (d) Biocatalysts
Assertion (A): β-glycosidic linkage is present in maltose.
Reason (R): Maltose is composed of two glucose units in which C-l of one glucose unit is linked to C-4 of another glucose unit.
Carbohydrates are classified on the basis of their behaviour on hydrolysis and also as reducing or non-reducing sugar. Sucrose is a .
(a) monosaccharide (b) disaccharide
(c) reducing sugar (d) non-reducing sugar
Which of the following are purine bases?
(a) Guanine (b) Adenine (c) Thymine (d) Uracil
Carbohydrates are essential for life in both plants and animals. Name the carbohydrates that are used as storage molecules in plants and animals, also name the carbohydrate which is present in wood or in the fibre of cotton cloth.
How are vitamins classified? Name the vitamin responsible for the coagulation of blood.
Sucrose is dextrorotatory but the mixture obtained after hydrolysis is laevorotatory. Explain.
Assertion (A): In presence of enzyme, substrate molecule can be attacked by the reagent effectively.
Reason (R): Active sites of enzymes hold the substrate molecule in a suitable position.
In disaccharides, if the reducing groups of monosaccharides, i.e., aldehydic or ketonic groups are bonded, these are non-reducing sugars. Which of the following disaccharide is a non-reducing sugar?
Which of the following carbohydrates are branched polymer of glucose?
(a) Amylose (b) Amylopectin (c) Cellulose (d) Glycogen
In fibrous proteins, polypeptide chains are held together by
(a) van der Waals forces (b) disulphide linkage
(c) electrostatic forces of attraction (d) hydrogen bonds
Assertion (A): All naturally occurring a-amino acids except glycine are optically active.
Reason (R): Most naturally occurring amino acids have L-configuration.
What happens when D-glucose is treated with . the following reagents.
(i)HI (ii) Bromine water (iii) HNO3
Name the sugar present in milk. How many monosaccharide units are present in it? What are such oligosaccharides called?
In nucleoside a base is attached at 1′ position of sugar moiety. Nucleotide is formed by linking of phosphoric acid unit to the sugar unit of nucleoside. At which position of sugar unit is the phosphoric acid linked in a nucleoside to give a nucleotide?
Some enzymes are named after the reaction, where they are used. What name is given to the class of enzymes which catalyse the oxidation of one substrate with simultaneous reduction of another substrate?
Structures of glycine and alanine are given below. Show the peptide linkage in glycylalanine.
Assertion (A): Glycine must’be taken through diet.
Reason (R): It is an essential amino acid.
