Dehydration of hydrates of halides of.calcium, barium and strontium, i.e., CaCl2.6H20, BaCl2.2H20, SrCl2.2H20, can be achieved by heating. These become wet oh keeping in air. Which of the following statements is correct about these halides?
(a) Act as dehydrating agents.
(b) Can absorb moisture from air.
(c) Tendency to form hydrate decreases from calcium to barium.
(d) All of the above.
(d) Chlorides of alkaline earth metals are hydrated salts. Due to their hygroscopic nature, they can be used as dehydrating agents to absorb moisture from air.
Extent of hydration decreases from Mg to Ba, i.e., MgCl2.6H20, CaCl2.6H20, BaCl2 2H20, SrCl2.2H20.
Lithium resembles magnesium in some of its properties. Mention two such properties and give reasons for this resemblance.
Why does the solution of alkali metals becomes blue in liquid ammonia? Give the chemical equation also.
Discuss the trend of the following:
(i) Thermal stability of carbonates of Group 2 elements.
(ii) The solubility and the nature of oxides, of Group 2 elements.
The alkali metals are low melting. Which of the following alkali metals is expected to melt if the room temperature rises to 30 °C?
(a) Na (b) K (c) Rb (d) Cs
Identify the correct’ formula of halides of alkaline earth metals from the following.
(a) BaCl2.2H20
(b) BaCl2 .4H20
(c) CaCl2 . 6H20
(d) SrCl2.4H20
Match the elements given in Column I with the colour they impart to the flame given in Column II.
| Column I | Column II |
| (i) Cs | (a) Apple green |
| (ii) Na | (b) Violet |
| (iii) K | (c) Brick red |
| (iv) Ca | (d) Yellow |
| (v) Sr | (e) Crimson red |
| (vi) Ba | (f) Blue |
Arrange the following in the increasing order of solubility in water.
MgCl2, CaCl2, SrCl2, BaCl2
(a) What makes lithium to show properties uncommon to the rest of the alkali metals?
(b) When is a cation highly polarising? Which alkali metal cation has the highest polarising power?
The reducing power of a metal depends oh various factors. Suggest the factor which makes Li, the strongest reducing agent in aqueous solution.
(a) Sublimation enthalpy (b) Ionisation enthalpy
(c) Hydration enthalpy (d) Electron-gain enthalpy
Which of the following are the correct reasons for anomalous behaviour of lithium?
(a) Exceptionally small size of its atom.
(b) Its high polarizing power.
(c) It has high degree of hydration.
(d) Exceptionally low ionization enthalpy.
Why are BeS04 and MgS04 readily soluble in water while CaS04, SrS04 and BaS04 are insoluble?
Match the elements given in Column I with the properties mentioned in Column II.
| Column I | Column II |
| (i) Li | (a) Insoluble sulphate |
| (ii) Na | (b) Strongest monoacidic base |
| (iii) Ca | (c) Most negative E ° value among alkali metals |
| (iv) Ba | (d) Insoluble oxalate ‘ |
| (e) 6s2 outer electronic configuration |
Explain why can alkali and alkaline earth metals not be obtained by chemical reduction method.
The order of decreasing ionization enthalpy in alkali metals is
(a) Na > Li > K > Rb (b) Rb < Na < K < Li
(c) Li > Na > K > Rb (d) K < Li < Na < Rb
Why is LiF almost insoluble in water whereas LiCl soluble not only in water but also in acetone?
Metallic elements are described by their standard electrode potential, frision enthalpy, atomic size, etc. The alkali metals are characterized by which of the following properties?
(a) High boiling point. ‘
(b) High negative standard electrode potential.
(c) High density.
(d) Large atomic size.
When alkali metal dissolves in liquid ammonia, the solution can acquire different colours. Explain the reason for this type of colour change.
Which one of the following alkaline earth metal carbonates is thermally most stable?
(a) MgCO3 (b) CaCO3 (c) SrCO3 (d) BaCO3
Why are alkali metals always univalent? Which alkali metal ion forms largest hydrated ion in aqueous solution?
In the synthesis of sodium carbonate, the recovery of ammonia is done by treating NH4C1 with Ca(OH)2. The by-product obtained in this process is
(a) CaCl2
(b) NaCl
(c) NaOH
(d) NaHC03
Choose the correct statements from the folio-wing.
(a) Beryllium is not readily attacked by acids because of the presence of an oxide film on the surface of the metal.
(b) Beryllium sulphate is readily soluble in water as the greater hydration enthalpy of Be2+ overcomes the lattice enthalpy factor.
(c) Beryllium exhibits coordination number more than four.
(d) Beryllium oxide is purely acidic in nature.
All compounds of alkali metals are easily soluble in water but lithium compounds are more soluble in organic solvents. Explain.
Describe two important uses of each of the following: ,
(i) caustic soda (ii) sodium carbonate (iii) quick lime
Explain the following:
(a) Lithium iodide is more covalent than lithium fluoride.
(b) Lattice enthalpy of LiF is maximum among all the alkali metal halides.
Write the chemical formula of the following compounds.
(i) Chile salt petre (ii) Marble (iii) Brine
State as to why
(a) Alkali metals show only +1 oxidation state. (b) Na and K impart colour to the flame but Mg does not.(c) Lithium on being heated in air mainly forms the monoxide and not the peroxide.(d) Li is the best reducing agent in aqueous solution.
Which of the carbonates given below is unstable in air and is kept in C02 atmosphere to avoid decomposition.
(a) BeCO3
(b) MgC03
(c) CaC03
(d) BaCO3
Which of the following statements is true about Ca(OH)2?
(a) It is used in the preparation of bleaching powder.
(b) It is a light blue solid.
(c) It does not possess disinfectant property.
(d) It is used in the manufacture of cement.
Compare the alkali metals and alkaline earth metals with respect to (i) ionization enthalpy, (ii) basicity of oxides, (iii) solubility of hydroxides.
Compare the solubility and thermal stability of the following compounds of the alkali metals with those of the alkaline earth metals.
(a) Nitrates (b) Carbonates (c) Sulphates
What happens when
(i) Sodium metal is dropped in water?
(ii) Sodium metal is heated in free supply of air?
(iii) Sodium peroxide dissolves in water?
Write balanced equations for reactions between.
(a) Na2O2 and water
(b) KO2 and water
(c) Na2O and CO2