Explain the significance of sodium, potassium, magnesium and calcium in biological fluids.
Sodium ions:
Potassium ions:
Magnesium ions:
Calcium:
Why are alkali metals always univalent? Which alkali metal ion forms largest hydrated ion in aqueous solution?
The alkali metals are low melting. Which of the following alkali metals is expected to melt if the room temperature rises to 30 °C?
(a) Na (b) K (c) Rb (d) Cs
Lithium resembles magnesium in some of its properties. Mention two such properties and give reasons for this resemblance.
Discuss the trend of the following:
(i) Thermal stability of carbonates of Group 2 elements.
(ii) The solubility and the nature of oxides, of Group 2 elements.
Why are lithium salts commonly hydrated and those of the other alkali metal ions usually anhydrous?
Which of the following compounds are readily soluble in water?
(a) BeS04
(b) MgS04
(c) BaS04
(d) SrS04
Match the elements given in Column I with the colour they impart to the flame given in Column II.
| Column I | Column II |
| (i) Cs | (a) Apple green |
| (ii) Na | (b) Violet |
| (iii) K | (c) Brick red |
| (iv) Ca | (d) Yellow |
| (v) Sr | (e) Crimson red |
| (vi) Ba | (f) Blue |
Arrange the following in the increasing order of solubility in water.
MgCl2, CaCl2, SrCl2, BaCl2
Why does the solution of alkali metals becomes blue in liquid ammonia? Give the chemical equation also.
Why is LiF almost insoluble in water whereas LiCl soluble not only in water but also in acetone?
In the synthesis of sodium carbonate, the recovery of ammonia is done by treating NH4C1 with Ca(OH)2. The by-product obtained in this process is
(a) CaCl2
(b) NaCl
(c) NaOH
(d) NaHC03
Choose the correct statements from the folio-wing.
(a) Beryllium is not readily attacked by acids because of the presence of an oxide film on the surface of the metal.
(b) Beryllium sulphate is readily soluble in water as the greater hydration enthalpy of Be2+ overcomes the lattice enthalpy factor.
(c) Beryllium exhibits coordination number more than four.
(d) Beryllium oxide is purely acidic in nature.
Which of the following are the correct reasons for anomalous behaviour of lithium?
(a) Exceptionally small size of its atom.
(b) Its high polarizing power.
(c) It has high degree of hydration.
(d) Exceptionally low ionization enthalpy.
Match the compounds given in Column I with their uses mentioned in Column II.
| Column I | Column II |
| (i) CaC03 | (a) Dentistry, ornamental work |
| (ii) Ca(OH)2 | (b) Manufacture of sodium carbonate from caustic soda |
| (iii) CaO | (c) Manufacture-of high quality paper |
| (iv) CaS04 | (d) Used in white washing |
Write balanced equations for reactions between.
(a) Na2O2 and water
(b) KO2 and water
(c) Na2O and CO2
Which one of the following alkaline earth metal carbonates is thermally most stable?
(a) MgCO3 (b) CaCO3 (c) SrCO3 (d) BaCO3
(a) What makes lithium to show properties uncommon to the rest of the alkali metals?
(b) When is a cation highly polarising? Which alkali metal cation has the highest polarising power?
Which of the following statements is true about Ca(OH)2?
(a) It is used in the preparation of bleaching powder.
(b) It is a light blue solid.
(c) It does not possess disinfectant property.
(d) It is used in the manufacture of cement.
All compounds of alkali metals are easily soluble in water but lithium compounds are more soluble in organic solvents. Explain.
Which one of the following alkali metals give hydrated salts?
(a) Li (b) Na (c) K (d) Cs
The reducing power of a metal depends oh various factors. Suggest the factor which makes Li, the strongest reducing agent in aqueous solution.
(a) Sublimation enthalpy (b) Ionisation enthalpy
(c) Hydration enthalpy (d) Electron-gain enthalpy
Match the elements given in Column I with the properties mentioned in Column II.
| Column I | Column II |
| (i) Li | (a) Insoluble sulphate |
| (ii) Na | (b) Strongest monoacidic base |
| (iii) Ca | (c) Most negative E ° value among alkali metals |
| (iv) Ba | (d) Insoluble oxalate ‘ |
| (e) 6s2 outer electronic configuration |
What is the effect of heat on the following compounds (Give equations for the reactions)? (i) CaC03 (ii) CaSO4 2H2O
Write the chemical formula of the following compounds.
(i) Chile salt petre (ii) Marble (iii) Brine
A chemical A is used for the preparation of washing soda to recover ammonia. When C02 is bubbled through an aqueous solution of A, the solution tons milky. It is used in white washing due to disinfectant nature. What is the chemical formula of A?
(a) Ca(C03)2
(b) CaO
(c) Ca(OH)2
(d) CaC03
Metallic elements are described by their standard electrode potential, frision enthalpy, atomic size, etc. The alkali metals are characterized by which of the following properties?
(a) High boiling point. ‘
(b) High negative standard electrode potential.
(c) High density.
(d) Large atomic size.
When heated in air, the alkali metals form various oxides. Mention the oxides formed by Li, Na and K.
Compare the alkali metals and alkaline earth metals with respect to (i) ionization enthalpy, (ii) basicity of oxides, (iii) solubility of hydroxides.
Starting with sodium chloride how would you proceed to prepare.
(i) Sodium metal (ii) Sodium hydroxide
(iii) Sodium peroxide (iv) Sodium carbonate?
Describe two important uses of each of the following: ,
(i) caustic soda (ii) sodium carbonate (iii) quick lime