In the Solvay process, can we obtain sodium carbonate directly by treating the solution containing (NH4)2C03 with sodium chloride? Explain.
No. In Solvay process, ammonium hydrogencarbonate is prepared from ammonium carbonate, which then reacts with sodium chloride to form sodium hydrogencarbonate. Due to low solubility of NaHC03, it gets precipitated and decomposes on heating to give Na2C03.
We cannot obtain sodium carbonate directly by treating the solution containing (NH4)2C03 with sodium chloride as both the products formed on reaction, i.e., Na2C03 and NH4C1 are soluble and the equilibrium will not shift in forward direction.
(NH4)2C03 + 2NaCl⇌Na2C03 + 2NH4Cl
Lithium resembles magnesium in some of its properties. Mention two such properties and give reasons for this resemblance.
Discuss the trend of the following:
(i) Thermal stability of carbonates of Group 2 elements.
(ii) The solubility and the nature of oxides, of Group 2 elements.
Why does the solution of alkali metals becomes blue in liquid ammonia? Give the chemical equation also.
The alkali metals are low melting. Which of the following alkali metals is expected to melt if the room temperature rises to 30 °C?
(a) Na (b) K (c) Rb (d) Cs
Why is LiF almost insoluble in water whereas LiCl soluble not only in water but also in acetone?
Why are alkali metals always univalent? Which alkali metal ion forms largest hydrated ion in aqueous solution?
(a) What makes lithium to show properties uncommon to the rest of the alkali metals?
(b) When is a cation highly polarising? Which alkali metal cation has the highest polarising power?
Arrange the following in the increasing order of solubility in water.
MgCl2, CaCl2, SrCl2, BaCl2
The reducing power of a metal depends oh various factors. Suggest the factor which makes Li, the strongest reducing agent in aqueous solution.
(a) Sublimation enthalpy (b) Ionisation enthalpy
(c) Hydration enthalpy (d) Electron-gain enthalpy
Identify the correct’ formula of halides of alkaline earth metals from the following.
(a) BaCl2.2H20
(b) BaCl2 .4H20
(c) CaCl2 . 6H20
(d) SrCl2.4H20
Choose the correct statements from the folio-wing.
(a) Beryllium is not readily attacked by acids because of the presence of an oxide film on the surface of the metal.
(b) Beryllium sulphate is readily soluble in water as the greater hydration enthalpy of Be2+ overcomes the lattice enthalpy factor.
(c) Beryllium exhibits coordination number more than four.
(d) Beryllium oxide is purely acidic in nature.
Which of the following are the correct reasons for anomalous behaviour of lithium?
(a) Exceptionally small size of its atom.
(b) Its high polarizing power.
(c) It has high degree of hydration.
(d) Exceptionally low ionization enthalpy.
Match the elements given in Column I with the properties mentioned in Column II.
| Column I | Column II |
| (i) Li | (a) Insoluble sulphate |
| (ii) Na | (b) Strongest monoacidic base |
| (iii) Ca | (c) Most negative E ° value among alkali metals |
| (iv) Ba | (d) Insoluble oxalate ‘ |
| (e) 6s2 outer electronic configuration |
Match the elements given in Column I with the colour they impart to the flame given in Column II.
| Column I | Column II |
| (i) Cs | (a) Apple green |
| (ii) Na | (b) Violet |
| (iii) K | (c) Brick red |
| (iv) Ca | (d) Yellow |
| (v) Sr | (e) Crimson red |
| (vi) Ba | (f) Blue |
A chemical A is used for the preparation of washing soda to recover ammonia. When C02 is bubbled through an aqueous solution of A, the solution tons milky. It is used in white washing due to disinfectant nature. What is the chemical formula of A?
(a) Ca(C03)2
(b) CaO
(c) Ca(OH)2
(d) CaC03
Which one of the following alkali metals give hydrated salts?
(a) Li (b) Na (c) K (d) Cs
The order of decreasing ionization enthalpy in alkali metals is
(a) Na > Li > K > Rb (b) Rb < Na < K < Li
(c) Li > Na > K > Rb (d) K < Li < Na < Rb
Why are BeS04 and MgS04 readily soluble in water while CaS04, SrS04 and BaS04 are insoluble?
Comment on each of the following observations:
(a) The mobilities of the alkali metal ions in aqueous solution are Li+ < Na+
(b) Lithium is the only alkali metal to form a nitride directly.
(c) Ee for M2+ (aq) + 2e– —> M(s) (where M = Ca, Sr, or Ba) is nearly constant.
Write balanced equations for reactions between.
(a) Na2O2 and water
(b) KO2 and water
(c) Na2O and CO2
Which one of the following alkaline earth metal carbonates is thermally most stable?
(a) MgCO3 (b) CaCO3 (c) SrCO3 (d) BaCO3
Write the chemical formula of the following compounds.
(i) Chile salt petre (ii) Marble (iii) Brine
State as to why
(a) Alkali metals show only +1 oxidation state. (b) Na and K impart colour to the flame but Mg does not.(c) Lithium on being heated in air mainly forms the monoxide and not the peroxide.(d) Li is the best reducing agent in aqueous solution.
The solubility of metal halides depends on their nature, lattice enthalpy and hydration enthalpy of the individual ions. Amongst fluorides of alkali metals, the lowest solubility of LiF in water is due to
(a) ionic nature of lithium fluoride. . .
(b) high lattice enthalpy. ‘
(c) high hydration enthalpy for lithium ion.
(d) low ionization enthalpy of lithium atom.
Compare the alkali metals and alkaline earth metals with respect to (i) ionization enthalpy, (ii) basicity of oxides, (iii) solubility of hydroxides.
What happens when (i) magnesium is burnt in air, (ii) Quick lime is heated with silica (iii) chlorine reacts with slaked lime (iv) calcium nitrate is heated?
Describe two important uses of each of the following: ,
(i) caustic soda (ii) sodium carbonate (iii) quick lime
What happens when
(i) Sodium metal is dropped in water?
(ii) Sodium metal is heated in free supply of air?
(iii) Sodium peroxide dissolves in water?
What is the effect of heat on the following compounds (Give equations for the reactions)? (i) CaC03 (ii) CaSO4 2H2O
Explain the following:
(a) Lithium iodide is more covalent than lithium fluoride.
(b) Lattice enthalpy of LiF is maximum among all the alkali metal halides.