Chemistry

The s-Block Elements

Question:

Which is more basic NaOH or Mg(OH)2?

Answer:

NaOH is more basic.

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The s-Block Elements

Q 1.

Name the compounds used for the manufacture of washing soda by Solvay process.

Q 2.

Name the alkali metal which shows diagonal relationship with magnesium?

Q 3.

What is Quick lime? What happens when it is added to water?

Q 4.

What is the effect of heat on the following compounds (Give equations for the reactions)?  (i) CaC03 (ii) CaSO4 2H2O

Q 5.

Lithium resembles magnesium in some of its properties. Mention two such properties and give reasons for this resemblance.

Q 6.

What happens when crystals of washing soda are exposed to air?

Q 7.

How would you prepare sodium silicate from silica?

Q 8.

Which is more basic NaOH or Mg(OH)2?

Q 9.

Explain why is sodium less reactive than potassium.

Q 10.

What is the general name for elements of group 1 ?

Q 11.

Which alkaline earth metals do not impart colour to the flame?

Q 12.

When sodium is dissolved in liquid ammonia, a solution of deep blue colour is obtained. The colour of the solution is due to
(a) ammoniated electron                                          
(b) sodium ion
(c) sodium amide                                                                      
(d) ammoniated sodium ion

Q 13.

Starting with sodium chloride how would you proceed to prepare.
(i) Sodium metal (ii) Sodium hydroxide
(iii) Sodium peroxide (iv) Sodium carbonate?

Q 14.

What happens when sodium metal is heated in free supply of air?

Q 15.

Why does the solution of alkali metals becomes blue in liquid ammonia? Give the chemical equation also.

Q 16.

Metals form basic hydroxides. Which of the following metal hydroxides is the least basic?
(a) Mg(OH)2 (b) Ca(OH)2                             (c) Sr(OH)2                           (d) Ba(OH)2

Q 17.

Explain the significance of sodium, potassium, magnesium and calcium in biological fluids.

Q 18.

Why is the solution of alkali metals in liquid ammonia conducting in nature?

Q 19.

Alkali metals react with water vigorously to form hydroxides and dihydrogen. Which of the following alkali metals reacts with water least vigorously?
(a) Li . (b) Na (c) K (d) Cs

Q 20.

In the Solvay process, can we obtain sodium carbonate directly by treating the solution containing (NH4)2C03 with sodium chloride? Explain.

Q 21.

Match the elements given in Column I with the properties mentioned in Column II.

Column I Column II
(i) Li (a) Insoluble sulphate
(ii) Na (b) Strongest monoacidic base
(iii) Ca (c) Most negative E ° value among alkali metals
(iv) Ba (d) Insoluble oxalate                                                                         ‘
  (e) 6s2 outer electronic configuration

 

Q 22.

Match the elements given in Column I with the colour they impart to the flame given in Column II.

Column I Column II
(i) Cs (a) Apple green
(ii) Na (b) Violet
(iii) K (c) Brick red
(iv) Ca (d) Yellow
(v) Sr (e) Crimson red
(vi) Ba (f) Blue

 

Q 23.

Discuss the general characteristics and gradation in properties of alkaline earth metals.

Q 24.

Beryllium and magnesium do not give colour to flame whereas other alkaline earth metals do so. Why?

Q 25.

Draw the structure of (i) BeCl2 (vapour), (ii) BeCl2 (solid).

Q 26.

What happens when
(i) Sodium metal is dropped in water?
(ii) Sodium metal is heated in free supply of air?
(iii) Sodium peroxide dissolves in water?

Q 27.

Why are alkali metals soft?

Q 28.

The order of decreasing ionization enthalpy in alkali metals is

(a) Na > Li > K > Rb (b) Rb < Na < K < Li

(c) Li > Na > K > Rb (d) K < Li < Na < Rb

Q 29.

Why are alkali metals always univalent? Which alkali metal ion forms largest hydrated ion in aqueous solution?

Q 30.

Which of the following compounds are readily soluble in water?
(a) BeS04                            
(b) MgS04                            
(c) BaS04                                
(d) SrS04

Q 31.

Describe two important uses of each of the following: ,
(i) caustic soda (ii) sodium carbonate (iii) quick lime

Q 32.

State as to why
(a) Alkali metals show only +1 oxidation state. (b) Na and K impart colour to the flame but Mg does not.(c) Lithium on being heated in air mainly forms the monoxide and not the peroxide.(d) Li is the best reducing agent in aqueous solution.

Q 33.

Which of the carbonates given below is unstable in air and is kept in C02 atmosphere to avoid decomposition.
(a) BeCO3
(b) MgC03
(c) CaC03
(d) BaCO3

Q 34.

Choose the correct statements from the folio-wing.
(a) Beryllium is not readily attacked by acids because of the presence of an oxide film on the surface of the metal.
(b) Beryllium sulphate is readily soluble in water as the greater hydration enthalpy of Be2+ overcomes the lattice enthalpy factor.
(c) Beryllium exhibits coordination number more than four.
(d) Beryllium oxide is purely acidic in nature.

Q 35.

How do you account for the strong reducing power of lithium in aqueous  solution? .

Q 36.

What is soda ash?

Q 37.

Potassium carbonate cannot be prepared by Solvay process. Why?

Q 38.

Why is LiF almost insoluble in water whereas LiCl soluble not only in water but also in acetone?

Q 39.

Some of the Group 2 metal halides are covalent and soluble in organic solvents. Among the following metal halides, the one which is soluble in ethanol is
(a) BeCl2
(b) MgCl2                                    
(c) CaCl2                                
(d) SrCl2

Q 40.

By adding gypsum to cement
(a) setting time of cement becomes less.
(b) setting time of cement increases.
(c) colour of cement becomes light.
(d) shining surface is obtained.

Q 41.

Identify the correct’ formula of halides of alkaline earth metals from the following.
(a) BaCl2.2H20
(b) BaCl2  .4H20
(c) CaCl2 . 6H20
(d) SrCl2.4H20

Q 42.

Which of the following are the correct reasons for anomalous behaviour of lithium?
(a) Exceptionally small size of its atom.
(b) Its high polarizing power.
(c) It has high degree of hydration.
(d) Exceptionally low ionization enthalpy.

Q 43.

Why are BeS04 and MgS04 readily soluble in water while CaS04, SrS04 and BaS04 are insoluble?

Q 44.

Compare the alkali metals and alkaline earth metals with respect to (i) ionization enthalpy, (ii) basicity of oxides, (iii) solubility of hydroxides.

Q 45.

In what ways lithium shows similarities to magnesium in its chemical behaviour?

Q 46.

Describe the importance of the following:
(i) Limestone (ii) Cement (iii) Plaster of Paris.

Q 47.

Why are lithium salts commonly hydrated and those of the other alkali metal ions usually anhydrous?

Q 48.

Which of the alkali metal is having least melting point?
(a) Na (b) K (c) Rb (d) Cs

Q 49.

Which one of the following alkaline earth metal carbonates is thermally most stable?
(a) MgCO3 (b) CaCO3 (c) SrCO3 (d) BaCO3

Q 50.

Name the alkaline earth metals whose salt do not impart colour to a non-luminous flame.