Chemistry

The p-Block Elements.

Question:

Why has it been difficult to study the chemistry of radon?

Answer:

Radon is radioactive with very short half-life which makes the study of chemistry of radon difficult.

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The p-Block Elements.

Q 1.

How is O3 estimated quantitatively?

Q 2.

Name three oxoacids of nitrogen. Write the disproportionation reaction of that oxoacid of nitrogen in which nitrogen is in +3 oxidation state.

Q 3.

Explain why inspite of nearly the same electronegativity, nitrogen forms hydrogen bonding while chlorine does not.

Q 4.

 Why is BiH3 the strongest reducing agent amongst all the hydrides of group 15 elements? (C.B.S.E. 2013)

Q 5.

Mention three areas in which H2SO4 plays an important role.

Q 6.

What happens when H3PO4 is heated?

Q 7.

Discuss the trends in chemical reactivity of group 15 elements.

Q 8.

Explain why does the stability of oxoacids of chlorine increase in the order given below:
HClO < HClO2 < HClO3 < HClO4

Q 9.

Match the compounds given in Column I with the hybridization and shape given in Column II and mark the correct option.
ncert-exemplar-problems-class-12-chemistry-p-block-elements-44

Q 10.

Match the items of Column I and Column II and mark the correct option.
ncert-exemplar-problems-class-12-chemistry-p-block-elements-49
ncert-exemplar-problems-class-12-chemistry-p-block-elements-50

Q 11.

Assertion (A): HNO3 makes from passive.
Reason (R): HNO3 forms a protective layer of ferric nitrate on the surface of iron.

Q 12.

Complete the following reactions:
(i)C2H2 + O2 -> (ii) 4Al + 3 O2 ->

Q 13.

What happens when sulp’hur dioxide is passed through an aqueous solution of Fe(III) salt?

Q 14.

Write the conditions to maximise the yield of H2SO4 by Contact process.

Q 15.

 How is nitrogen prepared in the laboratory? Write the chemical equations of the reactions . involved.

Q 16.

 Why does nitrogen show catenation properties less than phosphorus ? (C.B.S.E. Foreign 2009)

Q 17.

Justify the placement of O, S, Se, Te and Po in the same group’of the periodic table in terms of electronic configuration, oxidation state and hydride formation.

Q 18.

Explain why fluorine forms only one oxoacid, HOF.

Q 19.

Write a balanced equation for the hydrolytic reaction of PC is in heavy water.

Q 20.

Give the resonating structures of N02 and N2O5.

Q 21.

Write main differences between the properties of white phosphorus and red phosphorus.

Q 22.

Reduction potentials of some ions are given below. Arrange them in decreasing order of oxidizing power.
ncert-exemplar-problems-class-12-chemistry-p-block-elements-18

Q 23.

In the preparation of H2S06 by contact process, why is S03 not absorbed directly in water to form H2S04?

Q 24.

Write a balanced chemical equation, for the reaction showing catalytic oxidation of NH3 by atmospheric oxygen.

Q 25.

Write the structure of pyrophosphoric acid.

Q 26.

Out of H2O and H2S, which one has higher bond angle and why?

Q 27.

Phosphorus forms a number of oxoacids. Out of these oxoacids phosphinic acid has strong reducing property. Write its structure and also write a reaction showing its reducing behaviour.

Q 28.

 What is the covalence of nitrogen in N2O5 ?

Q 29.

 What happens when PCl5 is heated?

Q 30.

 Write the order of thermal stability of the – hydrides of Group 16 elements.

Q 31.

Give two examples to show the anomalous behaviour of fluorine.

Q 32.

Why has it been difficult to study the chemistry of radon?

Q 33.

Explain why NH3 is basic while BiH3 is only feebly basic.

Q 34.

Why is dioxygen a gas but sulphur a solid?

Q 35.

 How are XeOand XeOF4prepared?

Q 36.

Why does O3 act as a powerful oxidising agent?

Q 37.

How is O3 estimated quantitatively?

Q 38.

Mention three areas in which H2SO4 plays an important role.

Q 39.

Why does the reactivity of nitrogen differ from phosphorus?

Q 40.

How is nitrogen prepared in the laboratory? Write the chemical equations of the reactions . involved.

Q 41.

Why does R3P = O exist but R3N = O does not (R = alkyl group)?

Q 42.

Why does nitrogen show catenation properties less than phosphorus?

Q 43.

Describe the manufacture of H2SO4 by contact process?

Q 44.

Why are halogens strong oxidising agents?

Q 45.

Write the reactions of F2 and Cl2 with water.

Q 46.

Which one of the following does not exist ?
(i)XeOF4 (ii)NeF2
(iii)XeF4 (iv)XeF6

Q 47.

A brown ring is formed in the ring test for NO3 ion. It is due to the formation of
ncert-exemplar-problems-class-12-chemistry-p-block-elements-10

Q 48.

On heating ammonium dichromate and barium azide separately we get
(a) N2 in both cases
(b) N2 with ammonium dichromate and NO with barium azide
(c) N2O  with ammonium dichromate and N2 with barium azide
(d) N2O with ammonium dichromate and N2O with barium azide

Q 49.

Which of the following options are not in accordance with the properly mentioned against them?
ncert-exemplar-problems-class-12-chemistry-p-block-elements-20

Q 50.

Which of the following is correct for P4 molecule of white phosphorus?
(a) It has 6 lone pairs of electrons (b) It has six P – P single bonds
(c) It has three P – P single bonds (d) It has four lone pairs of electrons,