Chemistry

The p-Block Elements.

Question:

List the uses of neoirand argon gases.

Answer:

Uses of Neon Neon is used in discharge tubes and fluorescent bulbs for advertisement display purposes. Glow’of different colours neon signs' can be produced by mixing neon with other gases. Neon bulbs and used in botanical gardens and in green' houses.
Uses of Argon Argon is used mainly to provide an inert atmosphere in high temperature metallurgical processes such as arc welding of metals and alloys. In the laboratory, it is used for handling substance which are air sensitive.
It is used in filling incandescent and fluorescent lamps where its presence retards the sublimation of the filament and thus increases the life of the lamp.It is also used in "neon signs"for obtaining lights of different colours.

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The p-Block Elements.

Q 1.

 How are XeOand XeOF4prepared?

Q 2.

How is O3 estimated quantitatively?

Q 3.

Why is the reactivity of nitrogen different from that of phosphorus?

Q 4.

 List the uses of neoirand argon gases.

Q 5.

Write the reactions of F2 and Cl2 with water.

Q 6.

With what neutral molecule is CIO isoelectronic? Is that molecule a Lewis base?

Q 7.

List the uses of neoirand argon gases.

Q 8.

In a cyclotrimeta phosphoric acid molecule, how many single and double bonds are present? .
(a) 3 double bonds; 9 single bonds
(b) 6 double bonds; 6 single bonds
(c) 3 double bonds; 12 single bonds
(d) Zero double bonds; 12 single bonds

Q 9.

In which of the following reactions cone. H2S04 is used as an oxidizing reagent?
ncert-exemplar-problems-class-12-chemistry-p-block-elements-25

Q 10.

Give reason to explain why ClF3 exists but FCl3 does not exist.

Q 11.

Nitric acid forms an oxide of nitrogen on reaction with P4O10. Write the reaction involved. Also write the resonating structures of the oxide of nitrogen formed.

Q 12.

 What happens when PCl5 is heated?

Q 13.

Can PCl5 act as an oxidising as well as a reducing agent Justify.

Q 14.

Why is dioxygen a gas but sulphur a solid?

Q 15.

How is O3 estimated quantitatively?

Q 16.

Why does the reactivity of nitrogen differ from phosphorus?

Q 17.

Give the disproportionation reaction of H3 P03 .

Q 18.

Describe the manufacture of H2SO4 by contact process?

Q 19.

Arrange the following in the order of property  indicated for each set: –
(i) F2 , Cl2 , Br2 , I2 – increasing bond dissociation enthalpy.
(ii) HF, HCI, HBr, HI – increasing acid . strength.
(iii) NH3, PH3, AsH3, SbH3, BiH3 – increasing Sol. base strength.

Q 20.

Give the formula and describe the structure of a noble gas species which is isostructural with:  (i) ICI4 (ii) IBr2 (iii) Br03

Q 21.

Which of the following acid forms three series of salts?
(a) H2PO2  (b) H3BO3 (C)H3PO4(d)H3PO3

Q 22.

Which of the following statements are correct for SO2  gas?
(a) It acts as a bleaching agent in moist conditions.
(b) Its molecule has a linear geometry.
(c) Its dilute solution is used as disinfectant.
(d) It can be prepared by the reaction of dilute H2SO4 with metal sulphide.

Q 23.

PH3 forms bubbles when passed slowly in water but NH3 dissolves. Explain.

Q 24.

Explain why does the stability of oxoacids of chlorine increase in the order given below:
HClO < HClO2 < HClO3 < HClO4

Q 25.

Phosphorus has three allotropic fonns —(i) white phosphorus (ii) red phosphorus and (iii) black phosphorus. Write the difference between white and red phosphorus on the basis of their structure and reactivity.

Q 26.

Match the compounds given in Column I with the hybridization and shape given in Column II and mark the correct option.
ncert-exemplar-problems-class-12-chemistry-p-block-elements-44

Q 27.

Match the items of Column I and Column II and mark the correct option.
ncert-exemplar-problems-class-12-chemistry-p-block-elements-49
ncert-exemplar-problems-class-12-chemistry-p-block-elements-50

Q 28.

Assertion (A): HI cannot be prepared by the reaction of KI with concentrated H2SO4.
Reason (R): HI has lowest H – X bond strength among halogen acids.

Q 29.

 Why is N2 less reactive at room temperature?

Q 30.

Why is bond angle in PH+4 ion higher than in PH3 ? (Pb. Board 2009)

Q 31.

 What happens when white phosphorus is heated with concentrated NaOH solution in an inert atmosphere of CO2?

Q 32.

Write a balanced equation for the hydrolytic reaction of PC is in heavy water.

Q 33.

What is the basicity of H3PO4?

Q 34.

Why is H2O a liquid and H2S a gas?

Q 35.

Sea is the greatest source of some halogens. Comment.

Q 36.

Why is ICI more reactive than l2?

Q 37.

 How is nitrogen prepared in the laboratory? Write the chemical equations of the reactions . involved.

Q 38.

How is ammonia manufactured industrially?

Q 39.

Illustrate how copper metal can give different products on reaction with HN03.

Q 40.

 Why does R3P=0 exist but R3N=0 does not (R is an alkyl group) ?

Q 41.

Explain why NH3 is basic while BiH3 is only feebly basic.

Q 42.

. Nitrogen exists as diatomic molecule and phosphorus as P4. Why?

Q 43.

 Why does nitrogen show catenation properties less than phosphorus ? (C.B.S.E. Foreign 2009)

Q 44.

 How is SO2 an air pollutant?

Q 45.

Explain why fluorine forms only one oxoacid, HOF.

Q 46.

Why are halogens coloured?

Q 47.

What inspired N. Bartlett for carrying out reaction between Xe and PtF6?

Q 48.

 With which neutral molecule is ClO isoelectronic? Is this molecule Lewis acid or base ? (Pb. Board 2009)

Q 49.

Why are pentahalides more covalent than trihalidcs ?

Q 50.

How does ammonia react with a solution of Cu2+?