The skeletal structure of CH3COOH as shown below is correct, but some of the bonds are shown incorrectly. Write the correct Lewis structure for acetic acid.
Match the species in Column I with the geometry/shape in Column II.
Column I | Column II |
(i) H30+ | (a) Linear |
(ii) HC = CH | (b) Angular |
(iii) Cl0–2 | (c) Tetrahedral |
(iv) NH+4 | (d) Trigonal bipyramidal |
– | (e) Pyramidal |
Which of the following statements are correct about CO32- ?
(a) The hybridization of central atom is sp3.
(b) Its resonance structure has one C – O single bond and two C = O double bonds.
(c) The average formal charge on each oxygen atom is 0.67 units.
(d) All C – O bond lengths are equal.
Account for the following:
(i) Water is a liquid while H2S is a gas
(ii) NH3 has higher boiling point than PH3.
In which of the following substances will hydrogen bond be strongest?
(a) HCl
(b) H20
(c) HI
(d) H2S
Using molecular orbital theory, compare the bond energy and magnetic character of 0+2 and O–2
Match the shape of molecules in Column I with the type of hybridization in Column II.
Column I | Column II |
(i) Tetrahedral | (a) sp2 |
(ii) Trigonal | (b) sp |
(iii) Linear | (c) sp3 |
Which hybrid orbitals are used by carbon atoms in the following molecules?
(a) CH3-CH3 (b) CH3-CH = CH2 (c) CH3-CH2-OH (d) CH3-CHO (e) CH3COOH.
The skeletal structure of CH3COOH as shown below is correct, but some of the bonds are shown incorrectly. Write the correct Lewis structure for acetic acid.
Name the two conditions which must be satisfied for hydrogen bonding to take place in a molecule.
3PO3 can be represented by structures 1 and 2 shown below. Can these two structures be taken as the canonical forms of the resonance hybrid representing H3PO3? If not, give reasons for the same.
What is meant by hybridisation of atomic orbitals? Describe the shapes of sp, sp2, sp3 hybrid orbitals.
Describe the change in hybridisation (if any) of the Al atom in the following reaction. AlCl3 + Cl– ——>AlCl4- .
Draw diagrams showing the formation of a double bond and a triple bond between carbon atoms in C2 H4 and C2 H2 molecules.
(a) How many a and n bonds are present in
(b) Why Hf is more stable than H2?
(c) Why is B2 molecule paramagnetic?
Predict the shapes of the following molecules on the basis of hybridization. BC13, ch4, co2, nh3
Explain the diamagnetic behaviour of P2 molecule on the basis of molecular orbital theory.
(a) Define dipole moment. What are the units of dipole moment?
(b) Dipole moment values help in predicting the shapes of covalent molecules. Explain.
Apart from tetrahedral geometry, another possible geometry for CH4 is square planar with the four H atoms at the comers of the square and the C atoms at its centre. Explain why CH4 is not square planar?
Explain the non linear shape of H2S and non planar shape of PCl3 using valence shell electron pair repulsion theory.
What is an ionic bond? With two suitable examples explain the difference between an ionic and covalent bond?
Discuss the shape of the following molecules using the VSEPR model:
BeCl2, BCl3 , SiCl4, AsF5, H2S, PH3
Is there any change in the hybridisation ofB and N atoms as a result of the following reaction ? BF3 + NH3 ——-> F3 B.NH3
Considering X-axis as the intemuclear axis which out of the following will not form a sigma bond and why? (a) Is and Is (b) Is and 2px (c) 2py and 2py (d) Is and 2s
Define Lattice energy. How is Lattice energy influenced by (i) Charge on the ions (ii) Size of the ions?