Why do physisorption and chemisorption behave differently with rise in temperature?
Physisorption involves weak van der Waals forces which become weaker with rise of temperature. The chemisorption involves formation of chemical bonds involving activation energy. With increase of temperature, we reach the activated complex faster. Therefore, chemisorption process becomes faster.
Assertion (A): Colloidal solutions show colligative properties.
Reason (R): Colloidal particles are large in size.
What type of solutions are formed on dissolving different concentrations of soap in water?
In the following questions, a statement of Assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the following choices:
(a) Both Assertion and Reason are correct and the Reason is the correct explanation for Assertion.
(b) Both Assertion and Reason arc correct but Reason is not the correct explanation for Assertion.
(c) Assertion is correct but Reason is incorrect.
(d) Both Assertion and Reason are incorrect.
(e) Assertion is incorrect but Reason is correct
Assertion (A): An ordinary filter paper impregnated with collodion solution stops the flow of colloidal particles.
Reason (R): Pore size of the filter paper becomes more than size of colloidal particle.
A colloid is formed by adding FeCl3 in excess of hot water. What will happen if excess sodium chloride is added to this colloid?
Explain what is observed
(i) when a beam of light is passed through a colloidal sol.
(ii) an electrolyte, NaCI is added to hydrated ferric oxide sol.
(iii) electric current is passed through a colloidal sol.
Give an example where physisorption changes to chemisorption with rise in temperature. Explain the reason for change.
Which of the following phenomenon occurs when a chalk stick is dipped in ink?
(a) Adsorption of coloured substance
(b) Adsorption of solvent
(c) Absorption and adsorption both of solvent
(d) Absorption of solvent.
Why is it essential to wash the precipitate with water before estimating it quantitatively?
In a reaction, catalyst changes
(a) physically (b) qualitatively
(c) chemically (d) quantitatively
What are lyophilic and lyophobic sols? Give one example of each type. Why are hydrophobic sols easily coagulated?
Which of the following phenomenon occurs when a chalk stick is dipped in ink?
(a) Adsorption of coloured substance
(b) Adsorption of solvent
(c) Absorption and adsorption both of solvent
(d) Absorption of solvent.
What is the role of adsorption in froth floatation process used especially for concentration of sulphide ores?
Distinguish between the meaning of the terms adsorption and absorption. Give one example of each.
H2 gas is adsorbed on activated charcoal to a very little extent in comparison
to easily liquefiable gases due to
(a) very strong van der Waals interaction
(b) very weak van der Waals forces
(c) very low critical temperature
(d) very high critical temperature.
Match the types of colloidal systems given in Column I with the name given in Column II.
Assertion (A): Detergents with low CMC are more economical to use. Reason (R): Cleansing action of detergents involves the formation of micelles. These are formed when the concentration of detergents becomes equal to CMC.
Which of the following colloids cannot be coagulated easily?
(a) Lyophobic colloids (b) Irreversible colloids
(c) Reversible colloids (d) Lyophilic colloids
Assertion (A): Coagulation power of Al3+ is more than Na+
Reason (R): Greater the Valency of the flocculating ion added, greater is its power to cause precipitation (Hardy-Schulze rule).
Arrange the following diagrams in correct sequence of steps involved in the mechanism of catalysis, in accordance with modem adsorption theory.
Which of the following options are correct?
(a) Micelle formation by soap in aqueous solution is possible at all temperatures.
(b) Micelle formation by soap in aqueous solution occurs above a particular concentration.
(c) On dilution of soap solution micelles may revert to individual ions.
(d) Soap solution behaves as a normal strong electrolyte at all concentrations.
What do you understand by shape selective catalysis? Why are zeolites good shape selective catalysts?
