Chemistry

Surface Chemistry

Question:

Discuss the effect of pressure and temperature on the adsorption of gases on solids.

Answer:

(i) Adsorption decreases with an increase in temperature since it is an exothermic process by applying Le Chatelier's principle the reaction will proceed in backward direction with increase in temperature.
(ii) At a constant temperature, adsorption increases with pressure.

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Surface Chemistry

Q 1.

Assertion (A): Colloidal solutions show colligative properties.
Reason (R): Colloidal particles are large in size.

Q 2.

Why is the ester-hydrolysis slow in the beginning and becomes faster after sometime?

Q 3.

What type of solutions are formed on dissolving different concentrations of soap in water?

Q 4.

A colloid is formed by adding FeCl3  in excess of hot water. What will happen if excess sodium chloride is added to this colloid?

Q 5.

In the following questions, a statement of Assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the following choices:
(a) Both Assertion and Reason are correct and the Reason is the correct explanation for Assertion.
(b) Both Assertion and Reason arc correct but Reason is not the correct explanation for Assertion.
(c) Assertion is correct but Reason is incorrect.
(d) Both Assertion and Reason are incorrect.
(e) Assertion is incorrect but Reason is correct

Assertion (A): An ordinary filter paper impregnated with collodion solution stops the flow of colloidal particles.
Reason (R): Pore size of the filter paper becomes more than size of colloidal particle.

Q 6.

Why is chemisorption referred to as activated adsorption?

Q 7.

What role does adsorption play in heterogeneous catalysis?

Q 8.

Give an example where physisorption changes to chemisorption with rise in temperature. Explain the reason for change.

Q 9.

Why does physisorption decrease with the increase of temperature?

Q 10.

Explain what is observed
(i) when a beam of light is passed through a colloidal sol.
(ii) an electrolyte, NaCI is added to hydrated ferric oxide sol.
(iii) electric current is passed through a colloidal sol.

Q 11.

Why do physisorption and chemisorption behave differently with rise in temperature?

Q 12.

What are the applications of adsorption in chemical analysis?

Q 13.

Give reason why a finely divided substance is more effective as an adsorbent?

Q 14.

What are lyophilic and lyophobic sols? Give one example of each type. Why are hydrophobic sols easily coagulated?

Q 15.

Give four examples of heterogeneous catalysis.

Q 16.

Which of the following phenomenon occurs when a chalk stick is dipped in ink?
(a) Adsorption of coloured substance
(b) Adsorption of solvent
(c) Absorption and adsorption both of solvent
(d) Absorption of solvent.

Q 17.

Gelatin which is a peptide added in ice-creams. What can be its role?

Q 18.

Why is it essential to wash the precipitate with water before estimating it quantitatively?

Q 19.

What is the role of desorption in the process of catalysis.

Q 20.

Which of the following electrolytes will have maximum coagulating value
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-7

Q 21.

In a reaction, catalyst changes  
(a) physically (b) qualitatively
(c) chemically (d) quantitatively

Q 22.

Why is it important to have clean surface in surface studies?

Q 23.

What is the role of adsorption in froth floatation process used especially for concentration of sulphide ores?

Q 24.

What causes Brownian motion in colloidal dispersion?

Q 25.

Why does leather get hardened after tanning?

Q 26.

What happens when dialysis is prolonged?

Q 27.

How does a delta form at the meeting place of sea and river water?

Q 28.

Distinguish between the meaning of the terms adsorption and absorption. Give one example of each.

Q 29.

What are enzymes? Write in brief the mechanism of enzyme catalysis.

Q 30.

H2 gas is adsorbed on activated charcoal to a very little extent in comparison
to easily liquefiable gases due to
(a) very strong van der Waals interaction
(b) very weak van der Waals forces
(c) very low critical temperature
(d) very high critical temperature.

Q 31.

Which of the following phenomenon occurs when a chalk stick is dipped in ink?
(a) Adsorption of coloured substance
(b) Adsorption of solvent
(c) Absorption and adsorption both of solvent
(d) Absorption of solvent.

Q 32.

How do emulsifying agents stabilize the emulsion?

Q 33.

Match the types of colloidal systems given in Column I with the name given in Column II.
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-20

Q 34.

Assertion (A): Detergents with low CMC are more economical to use. Reason (R): Cleansing action of detergents involves the formation of micelles. These are formed when the concentration of detergents becomes equal to CMC.

Q 35.

Why does bleeding stop by rubbing moist alum?

Q 36.

Write any two characteristics of Chemisorption.

Q 37.

What happens when gelatin is mixed with gold sol?

Q 38.

What is the role of activated charcoal in gas mask used in coal mines?

Q 39.

How does a delta form at the meeting place of sea and river water?

Q 40.

What is the role of diffusion in heterogeneous catalysis?

Q 41.

What is the role of adsorption in heterogeneous catalysis?

Q 42.

What do you understand by shape selective catalysis? Why are zeolites good shape selective catalysts?

Q 43.

Why are powdered substances more effective . adsorbents than their crystalline forms?

Q 44.

Which of the following statements are correct?
(a) Mixing two oppositely charged sols neutralizes their charges and stabilizes the colloid.
(b) Presence of equal and similar charges on colloidal particles provides stability to the colloids.
(c) Any amount of dispersed liquid can be added to emulsion without destabilizing it.
(d) Brownian movement stabilizes sols.

Q 45.

What happens when a lyophilic sol is added to a lyophobic sol?
(a) Lyophobic sol is protected.
(b) Lyophilic sol is protected.
(c) Film of lyophilic sol is formed over lyophobic sol.
(d) Film of lyophobic sol is formed over lyophilic sol.

Q 46.

How will you distinguish between dispersed phase and dispersion medium in an emulsion?

Q 47.

Method of formation of solution is given in Column I. Match it with the type of solution given in Column II.
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-17

Q 48.

What modification can you suggest in the Hardy Schulze, law?

Q 49.

What do you understand by activation of adsorbent? How is it achieved?

Q 50.

What are emulsions? What are their different types? Give example of each type.