Name the alkali metal which shows diagonal relationship with magnesium?
Li.
Match the elements given in Column I with the colour they impart to the flame given in Column II.
| Column I | Column II |
| (i) Cs | (a) Apple green |
| (ii) Na | (b) Violet |
| (iii) K | (c) Brick red |
| (iv) Ca | (d) Yellow |
| (v) Sr | (e) Crimson red |
| (vi) Ba | (f) Blue |
The solubility of metal halides depends on their nature, lattice enthalpy and hydration enthalpy of the individual ions. Amongst fluorides of alkali metals, the lowest solubility of LiF in water is due to
(a) ionic nature of lithium fluoride. . .
(b) high lattice enthalpy. ‘
(c) high hydration enthalpy for lithium ion.
(d) low ionization enthalpy of lithium atom.
Write the chemical formula of the following compounds.
(i) Chile salt petre (ii) Marble (iii) Brine
The order of decreasing ionization enthalpy in alkali metals is
(a) Na > Li > K > Rb (b) Rb < Na < K < Li
(c) Li > Na > K > Rb (d) K < Li < Na < Rb
Suspension of slaked lime in water is known as
(a) lime water
(b) quick lime
(c) milk of lime
(d) aqueous solution of slaked lime
Which of the carbonates given below is unstable in air and is kept in C02 atmosphere to avoid decomposition.
(a) BeCO3
(b) MgC03
(c) CaC03
(d) BaCO3
Arrange the following in the increasing order of solubility in water.
MgCl2, CaCl2, SrCl2, BaCl2
Why does the solution of alkali metals becomes blue in liquid ammonia? Give the chemical equation also.
Describe two important uses of each of the following: ,
(i) caustic soda (ii) sodium carbonate (iii) quick lime
The hydroxides and carbonates of sodium and potassium are easily soluble in water while the corresponding salts of magnesium and calcium are sparingly soluble in water. Explain.
Why are lithium salts commonly hydrated and those of the other alkali metal ions usually anhydrous?
(a) Compare four properties of alkali metals and alkaline earth metals.
(b) What happens when alkali metals are dissolved in ammonia?
(c) MgCl2 is electrolysed.
Beryllium and magnesium do not give colour to flame whereas other alkaline earth metals do so. Why?
Explain the significance of sodium, potassium, magnesium and calcium in biological fluids.
What happens when
(i) Sodium metal is dropped in water?
(ii) Sodium metal is heated in free supply of air?
(iii) Sodium peroxide dissolves in water?
(a) What makes lithium to show properties uncommon to the rest of the alkali metals?
(b) When is a cation highly polarising? Which alkali metal cation has the highest polarising power?
Metal carbonates decompose on heating to give metal oxide and carbon dioxide. Which of the metal carbonates is most stable thermally?
(a) MgC03
(b)CaC03
(c)SrCQ3
(d)BaC03
Explain why can alkali and alkaline earth metals not be obtained by chemical reduction method.
Which out of the following can be used to store an alkali metal?
H2O, C2H5OH and Benzene
Which one of the following alkaline earth metal carbonates is thermally most stable?
(a) MgCO3 (b) CaCO3 (c) SrCO3 (d) BaCO3
The reducing power of a metal depends oh various factors. Suggest the factor which makes Li, the strongest reducing agent in aqueous solution.
(a) Sublimation enthalpy (b) Ionisation enthalpy
(c) Hydration enthalpy (d) Electron-gain enthalpy
What happens when (i) magnesium is burnt in air, (ii) Quick lime is heated with silica (iii) chlorine reacts with slaked lime (iv) calcium nitrate is heated?
Which of the following statements is true about Ca(OH)2?
(a) It is used in the preparation of bleaching powder.
(b) It is a light blue solid.
(c) It does not possess disinfectant property.
(d) It is used in the manufacture of cement.
Compare the alkali metals and alkaline earth metals with respect to (i) ionization enthalpy, (ii) basicity of oxides, (iii) solubility of hydroxides.
All compounds of alkali metals are easily soluble in water but lithium compounds are more soluble in organic solvents. Explain.
Name the alkaline earth metals whose salt do not impart colour to a non-luminous flame.
Lithium resembles magnesium in some of its properties. Mention two such properties and give reasons for this resemblance.
What is the effect of heat on the following compounds (Give equations for the reactions)? (i) CaC03 (ii) CaSO4 2H2O
Identify the correct’ formula of halides of alkaline earth metals from the following.
(a) BaCl2.2H20
(b) BaCl2 .4H20
(c) CaCl2 . 6H20
(d) SrCl2.4H20
Why is LiF almost insoluble in water whereas LiCl soluble not only in water but also in acetone?
Why are alkali metals always univalent? Which alkali metal ion forms largest hydrated ion in aqueous solution?
The alkali metals are low melting. Which of the following alkali metals is expected to melt if the room temperature rises to 30 °C?
(a) Na (b) K (c) Rb (d) Cs