Nitric acid forms an oxide of nitrogen on reaction with P4O10. Write the reaction involved. Also write the resonating structures of the oxide of nitrogen formed.
Reactivity: White phosphorus is very reactive in comparison to red phosphorus. This is due to angular strain in white phosphorus on account of bond angles (60 °).
Write balanced equations for the following:
(i) NaCl is heated witlrsulphuric acid in the presence of MnO2
(ii) Chlorine gas is passed into a solution of Nal in water.
Which of the following statements are true?
(a) Only type of interactions between particles of noble gases are due to weak dispersion forces.
(b) Ionisation enthalpy of.molecular oxygen is very close to that of xenon.
(c) Hydrolysis of XeF6 is a redox reaction.
(d) Xenon fluorides are not reactive.
What happens when sulp’hur dioxide is passed through an aqueous solution of Fe(III) salt?
Match the formulas of oxides given in Column I with the type of oxide given in Column II and mark the correct option.
How is nitrogen prepared in the laboratory? Write the chemical equations of the reactions . involved.
If chlorine gas is passed through hot NaOH solution, two changes are observed in the oxidation number of chlorine during the reaction. These are —— and ——-
Why does nitrogen show catenation properties less than phosphorus ? (C.B.S.E. Foreign 2009)
Which of the following acid forms three series of salts?
(a) H2PO2 (b) H3BO3 (C)H3PO4(d)H3PO3
Explain why does the stability of oxoacids of chlorine increase in the order given below:
HClO < HClO2 < HClO3 < HClO4
How is nitrogen prepared in the laboratory? Write the chemical equations of the reactions . involved.
What happens when white phosphorus is heated with concentrated NaOH solution in an inert atmosphere of CO2 ?
What are the oxidation states of phosphorus in the following: –
(i) H3PO3 (ii)PCl3
(iii) Ca3P2(iv)Na3PO4
(v) POF3
In qualitative analysis when H2S is passed through an aqueous solution of salt acidified with dil. HCl, a black precipitate is obtained. On boiling the precipitate with dil. HNO3, it forms a solution of blue colour. Addition of excess of aqueous solution of ammonia to this solution gives
Which of the following is correct for P4 molecule of white phosphorus?
(a) It has 6 lone pairs of electrons (b) It has six P – P single bonds
(c) It has three P – P single bonds (d) It has four lone pairs of electrons,
Why is BiH3 the strongest reducing agent amongst all the hydrides of Group 15 elements?
What happens when sulp'hur dioxide is passed through an aqueous solution of Fe(III) salt?
Which of the following statements are correct?
(a) All three N – O bond lengths in HNO3 are equal.
(b) All P – Cl bond lengths in PCl5 molecule in gaseous state are equal.
(c) P4 molecule in white phosphorus have angular strain therefore white phosphorus is very reactive.
(d) PCl5 is ionic in solid state in which cation is tetrahedral and anion is octahedral.
Considering the parameters such as bond dissociation enthalpy, electron gain enthalpy and hydration enthalpy, compare the oxidising powers of F2 and Cl2.
Knowing the electron gain enthalpy values of O—>O– and O—>O2- as -141 and 702 kJ mol-1 respectively, how can you account for the formation of a large number of oxides having O2- species and not O–?
