Chemistry

Surface Chemistry

Question:

Why does leather get hardened after tanning?

Answer:

Animal skin is colloidal, in nature and carries positive charge. Tannin is a negatively charged colloidal solution. When leather is soaked in tannin, mutual coagulation of the two takes place and leather gets hardened.

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Surface Chemistry

Q 1.

Why is the ester-hydrolysis slow in the beginning and becomes faster after sometime?

Q 2.

Why is it essential to wash the precipitate with water before estimating it quantitatively?

Q 3.

A colloid is formed by adding FeCl3  in excess of hot water. What will happen if excess sodium chloride is added to this colloid?

Q 4.

How do emulsifying agents stabilize the emulsion?

Q 5.

Why is Fe(OH)3colloid positively charged, when prepared by adding FeCl3 to hot water?

Q 6.

What are the applications of adsorption in chemical analysis?

Q 7.

What happens when dialysis is prolonged?

Q 8.

Explain what is observed
(i) when a beam of light is passed through a colloidal sol.
(ii) an electrolyte, NaCI is added to hydrated ferric oxide sol.
(iii) electric current is passed through a colloidal sol.

Q 9.

Which of the following phenomenon occurs when a chalk stick is dipped in ink?
(a) Adsorption of coloured substance
(b) Adsorption of solvent
(c) Absorption and adsorption both of solvent
(d) Absorption of solvent.

Q 10.

Give reason why a finely divided substance is more effective as an adsorbent?

Q 11.

What are lyophilic and lyophobic sols? Give one example of each type. Why are hydrophobic sols easily coagulated?

Q 12.

What are the factors which influence the adsorption of a gas on a solid?

Q 13.

Freundlich adsorption isotherm is given by the expression  x/m=KP1/n. Which of the following conclusions can be drawn from this expression?
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-15

Q 14.

Why is chemisorption referred to as activated adsorption?

Q 15.

H2 gas is adsorbed on activated charcoal to a very little extent in comparison
to easily liquefiable gases due to
(a) very strong van der Waals interaction
(b) very weak van der Waals forces
(c) very low critical temperature
(d) very high critical temperature.

Q 16.

In the following questions, a statement of Assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the following choices:
(a) Both Assertion and Reason are correct and the Reason is the correct explanation for Assertion.
(b) Both Assertion and Reason arc correct but Reason is not the correct explanation for Assertion.
(c) Assertion is correct but Reason is incorrect.
(d) Both Assertion and Reason are incorrect.
(e) Assertion is incorrect but Reason is correct

Assertion (A): An ordinary filter paper impregnated with collodion solution stops the flow of colloidal particles.
Reason (R): Pore size of the filter paper becomes more than size of colloidal particle.

Q 17.

Why are some medicines more effective in the colloidal form?

Q 18.

How does a delta form at the meeting place of sea and river water?

Q 19.

What do you mean by activity and selectivity of catalysts?

Q 20.

Which of the following substances will precipitate the negatively charged emulsions?
(a) KCl (b) Glucose
(c) Urea (d) NaCl

Q 21.

Give an example where physisorption changes to chemisorption with rise in temperature. Explain the reason for change.

Q 22.

What is the role of diffusion in heterogeneous catalysis?

Q 23.

Match the items of Column I and Column II.
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-22

Q 24.

What is the role of adsorption in froth floatation process used especially for concentration of sulphide ores?

Q 25.

What is the role of desorption in the process of catalysis.

Q 26.

Which of the following electrolytes will have maximum coagulating value
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-7

Q 27.

How does it become possible to cause artificial rain by spraying silver iodide on the clouds?

Q 28.

How does a solid catalyst enhance the rate of combination of gaseous molecules?

Q 29.

Method of formation of solution is given in Column I. Match it with the type of solution given in Column II.
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-17

Q 30.

At the equilibrium position in the process of adsorption
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-1

Q 31.

Which of the following phenomenon occurs when a chalk stick is dipped in ink?
(a) Adsorption of coloured substance
(b) Adsorption of solvent
(c) Absorption and adsorption both of solvent
(d) Absorption of solvent.

Q 32.

Why does the white precipitate of silver halide become coloured in the presence of dye eosin.

Q 33.

Assertion (A): Colloidal solutions show colligative properties.
Reason (R): Colloidal particles are large in size.

Q 34.

Which of the following curves is in accordance with Freundlich adsorption isotherm?
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-11

Q 35.

Which phenomenon occurs when an electric field is applied to a-colloidal solution and electrophoresis is prevented?
(a) Reverse osmosis takes place.
(b) Electroosmosis takes place.
(c) Dispersion medium begins to move.
(d) Dispersion medium becomes stationary.

Q 36.

Why is it important to have clean surface in surface studies?

Q 37.

Assertion (A): Colloidal solutions do not show Brownian motion.
Reason (R): Brownian motion is responsible for stability of sols.

Q 38.

Assertion (A): Detergents with low CMC are more economical to use. Reason (R): Cleansing action of detergents involves the formation of micelles. These are formed when the concentration of detergents becomes equal to CMC.

Q 39.

Discuss the effect of pressure and temperature on the adsorption of gases on solids.

Q 40.

What type of solutions are formed on dissolving different concentrations of soap in water?

Q 41.

What happens when electric field is applied to colloidal solution?

Q 42.

How does the precipitation of colloidal smoke take place in Cottrell precipitator?

Q 43.

Write any two characteristics of Chemisorption.

Q 44.

What do you understand by activation of adsorbent? How is it achieved?

Q 45.

What are enzymes? Write in brief the mechanism of enzyme catalysis.

Q 46.

Action of soap is due to emulsification and micelle formation. Comment

Q 47.

Give four examples of heterogeneous catalysis.

Q 48.

Which of the following options are correct?
(a) Micelle formation by soap in aqueous solution is possible at all temperatures.
(b) Micelle formation by soap in aqueous solution occurs above a particular concentration.
(c) On dilution of soap solution micelles may revert to individual ions.
(d) Soap solution behaves as a normal strong electrolyte at all concentrations.

Q 49.

Which of the following statements are correct?
(a) Mixing two oppositely charged sols neutralizes their charges and stabilizes the colloid.
(b) Presence of equal and similar charges on colloidal particles provides stability to the colloids.
(c) Any amount of dispersed liquid can be added to emulsion without destabilizing it.
(d) Brownian movement stabilizes sols.

Q 50.

Which of the following colloids cannot be coagulated easily?
(a) Lyophobic colloids (b) Irreversible colloids
(c) Reversible colloids (d) Lyophilic colloids