Chemistry

Surface Chemistry

Question:

Method of formation of solution is given in Column I. Match it with the type of solution given in Column II.
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-17

Answer:

(i - »b), (ii —> c), (iii — » d), (iv —> a)
(i) When sulphur vapour passed through cold water, it leads to formation of molecular colloids.
(ii) When soap is mixed with water above critical micelle concentration, it leads to formation of associated colloids.
(iii) White part of egg whipped with water is an example of macro-molecular colloids in which high molecular mass proteneous molecule acts as a colloidal particle.
(iv) Soap mixed with water below critical micelle concentration is known as normal electrolyte solution.

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Surface Chemistry

Q 1.

Why is the ester-hydrolysis slow in the beginning and becomes faster after sometime?

Q 2.

Why is it essential to wash the precipitate with water before estimating it quantitatively?

Q 3.

A colloid is formed by adding FeCl3  in excess of hot water. What will happen if excess sodium chloride is added to this colloid?

Q 4.

How do emulsifying agents stabilize the emulsion?

Q 5.

Give reason why a finely divided substance is more effective as an adsorbent?

Q 6.

Which of the following phenomenon occurs when a chalk stick is dipped in ink?
(a) Adsorption of coloured substance
(b) Adsorption of solvent
(c) Absorption and adsorption both of solvent
(d) Absorption of solvent.

Q 7.

Why is Fe(OH)3colloid positively charged, when prepared by adding FeCl3 to hot water?

Q 8.

What are the applications of adsorption in chemical analysis?

Q 9.

What happens when dialysis is prolonged?

Q 10.

What are lyophilic and lyophobic sols? Give one example of each type. Why are hydrophobic sols easily coagulated?

Q 11.

Explain what is observed
(i) when a beam of light is passed through a colloidal sol.
(ii) an electrolyte, NaCI is added to hydrated ferric oxide sol.
(iii) electric current is passed through a colloidal sol.

Q 12.

Why is chemisorption referred to as activated adsorption?

Q 13.

Freundlich adsorption isotherm is given by the expression  x/m=KP1/n. Which of the following conclusions can be drawn from this expression?
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-15

Q 14.

What are the factors which influence the adsorption of a gas on a solid?

Q 15.

In the following questions, a statement of Assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the following choices:
(a) Both Assertion and Reason are correct and the Reason is the correct explanation for Assertion.
(b) Both Assertion and Reason arc correct but Reason is not the correct explanation for Assertion.
(c) Assertion is correct but Reason is incorrect.
(d) Both Assertion and Reason are incorrect.
(e) Assertion is incorrect but Reason is correct

Assertion (A): An ordinary filter paper impregnated with collodion solution stops the flow of colloidal particles.
Reason (R): Pore size of the filter paper becomes more than size of colloidal particle.

Q 16.

H2 gas is adsorbed on activated charcoal to a very little extent in comparison
to easily liquefiable gases due to
(a) very strong van der Waals interaction
(b) very weak van der Waals forces
(c) very low critical temperature
(d) very high critical temperature.

Q 17.

Why are some medicines more effective in the colloidal form?

Q 18.

How does a delta form at the meeting place of sea and river water?

Q 19.

Match the items of Column I and Column II.
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-22

Q 20.

Assertion (A): Colloidal solutions show colligative properties.
Reason (R): Colloidal particles are large in size.

Q 21.

What is the role of adsorption in froth floatation process used especially for concentration of sulphide ores?

Q 22.

What is the role of desorption in the process of catalysis.

Q 23.

What do you mean by activity and selectivity of catalysts?

Q 24.

Arrange the following diagrams in correct sequence of steps involved in the mechanism of catalysis, in accordance with modem adsorption theory.
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-9

Q 25.

Which of the following substances will precipitate the negatively charged emulsions?
(a) KCl (b) Glucose
(c) Urea (d) NaCl

Q 26.

Give an example where physisorption changes to chemisorption with rise in temperature. Explain the reason for change.

Q 27.

What is the role of diffusion in heterogeneous catalysis?

Q 28.

Assertion (A): Detergents with low CMC are more economical to use. Reason (R): Cleansing action of detergents involves the formation of micelles. These are formed when the concentration of detergents becomes equal to CMC.

Q 29.

Discuss the effect of pressure and temperature on the adsorption of gases on solids.

Q 30.

Which of the following electrolytes will have maximum coagulating value
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-7

Q 31.

Which of the following curves is in accordance with Freundlich adsorption isotherm?
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-11

Q 32.

How does it become possible to cause artificial rain by spraying silver iodide on the clouds?

Q 33.

How does a solid catalyst enhance the rate of combination of gaseous molecules?

Q 34.

Method of formation of solution is given in Column I. Match it with the type of solution given in Column II.
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-17

Q 35.

At the equilibrium position in the process of adsorption
ncert-exemplar-problems-class-12-chemistry-surface-chemistry-1

Q 36.

Which of the following phenomenon occurs when a chalk stick is dipped in ink?
(a) Adsorption of coloured substance
(b) Adsorption of solvent
(c) Absorption and adsorption both of solvent
(d) Absorption of solvent.

Q 37.

Why does the white precipitate of silver halide become coloured in the presence of dye eosin.

Q 38.

Assertion (A): Colloidal solutions do not show Brownian motion.
Reason (R): Brownian motion is responsible for stability of sols.

Q 39.

Why are powdered substances more effective . adsorbents than their crystalline forms?

Q 40.

Which phenomenon occurs when an electric field is applied to a-colloidal solution and electrophoresis is prevented?
(a) Reverse osmosis takes place.
(b) Electroosmosis takes place.
(c) Dispersion medium begins to move.
(d) Dispersion medium becomes stationary.

Q 41.

Why is it important to have clean surface in surface studies?

Q 42.

What type of solutions are formed on dissolving different concentrations of soap in water?

Q 43.

What happens when gelatin is mixed with gold sol?

Q 44.

Why does bleeding stop by rubbing moist alum?

Q 45.

Action of soap is due to emulsification and micelle formation. Comment

Q 46.

Give four examples of heterogeneous catalysis.

Q 47.

Which of the following options are correct?
(a) Micelle formation by soap in aqueous solution is possible at all temperatures.
(b) Micelle formation by soap in aqueous solution occurs above a particular concentration.
(c) On dilution of soap solution micelles may revert to individual ions.
(d) Soap solution behaves as a normal strong electrolyte at all concentrations.

Q 48.

Which of the following statements are correct?
(a) Mixing two oppositely charged sols neutralizes their charges and stabilizes the colloid.
(b) Presence of equal and similar charges on colloidal particles provides stability to the colloids.
(c) Any amount of dispersed liquid can be added to emulsion without destabilizing it.
(d) Brownian movement stabilizes sols.

Q 49.

Which of the following colloids cannot be coagulated easily?
(a) Lyophobic colloids (b) Irreversible colloids
(c) Reversible colloids (d) Lyophilic colloids

Q 50.

What happens when a lyophilic sol is added to a lyophobic sol?
(a) Lyophobic sol is protected.
(b) Lyophilic sol is protected.
(c) Film of lyophilic sol is formed over lyophobic sol.
(d) Film of lyophobic sol is formed over lyophilic sol.