Chemistry

Polymers

Question:

Match the polymers given in Column I with the type of linkage present in them given in Column II.
ncert-exemplar-problems-class-12-chemistry-polymers-30

Answer:

(i —> b), (ii —> d), (iii — » a), (iv -> d), (v - » c)

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Polymers

Q 1.

Name the polymers used in laminated sheets and give the name of monomeric units involved in its formation.

Q 2.

Match materials given in Column I with the polymers given in Column II.
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Q 3.

Out of chain growth polymerisation and step growth polymerisation, in which type will you place the following.
ncert-exemplar-problems-class-12-chemistry-polymers-18

Q 4.

Write the monomers used for gettingThe following polymers:
(i) Polyvinylchloride
(ii) Teflon (iii) Bakelite

Q 5.

Which of the following polymers are used as fibre?
(a) Polytetrafluoroethane (b) Poly chloroprene
(c) Nylon (d) Terylene

Q 6.

Identify the type of polymer given in the following figure.
ncert-exemplar-problems-class-12-chemistry-polymers-19

Q 8.

Match the polymers given in Column I with their chemical names given in Column II.
ncert-exemplar-problems-class-12-chemistry-polymers-26

Q 9.

In which of the following polymers ethylene glycol is one of the monomer units?
ncert-exemplar-problems-class-12-chemistry-polymers-5

Q 10.

Which of the following polymers soften on heating and harden on cooling? What are the polymers with this property collectively called? What are the polymers with this property collectively called? What are the structural similarities between such polymers? Bakelite, urea-formaldehyde resin, polythene, polyvinyl, polystyrene.

Q 11.

Assertion (A): Olefinic monomers undergo addition polymerization.
Reason (R): Polymerisation of vinyl chloride is initiated by peroxides/ persulphates.

Q 12.

Which of the following are characteristics of thermosetting polymers?
(a) Heavily branched cross linked polymers.
(b) Linear slightly branched long chain molecules.
(c) Become infusible on moulding so cannot be reused.
(d) Soften on heating and harden on cooling, can be reused.

Q 13.

Write the free radical mechanism for the polymerisation of ethene.

Q 14.

What is a biodegradable polymer ? Give an example of a biodegradable aliphatic polyester.

Q 15.

Which of the following polymers are condensation polymers?
(a) Bakelite (b) Teflon
(c) Butyl rubber (d) Melamine formaldehyde resin

Q 16.

What are polymers?

Q 17.

In which classes, the polymers are classified on the basis of molecular forces?

Q 18.

Assertion (A): Polyamides are best used as fibres because of high tensile strength.
Reason (R): Strong intermolecular forces (like hydrogen bonding within polyamides) lead to close packing of chains and increase the crystalline character, hence, provide high tensile strength to polymers.

Q 19.

Can nucleic acids, proteins and starch be considered as step growth polymers?

Q 20.

How are polymers classified on the basis of structure?

Q 21.

Write the names and structures of the monomers of the following polymers:
(i) Buna-S (ii) Buna-N (iii) Dacron (iv) Neoprene

Q 22.

Which of the following polymers are thermoplastic?
(a) Teflon (b) Natural rubber (c) Neoprene (d) Polystyrene

Q 23.

What is the role of benzoyl peroxide in addition polymerization of alkenes? Explain its mode of action with the help of an example.

Q 24.

Assertion (A): For making rubber synthetically, isoprene molecules are polymerised.
i Reason (R): Neoprene (a polymer of chloroprene) is a synthetic rubber.

Q 25.

Which of the following monomers form biodegradable polymers?
(a) 3-hydroxybutanoic acid +3-hydroxypentanoic acid
(b) Glycine + aminocaproic acid  
(c) Ethylene glycol + phthalic acid
(d) Caprolactam

Q 26.

What is the structural difference between HDP and LDP? How does the structure account for different behaviour and nature, hence the use of a polymer?

Q 27.

Discuss the main purpose of vulcanisation of rubber.

Q 28.

Which of the following are examples of synthetic rubber?
(a) Polychloroprene (b) Polyacrylonitrile
(c) Buna-N (d) cis-polyisoprene

Q 29.

How is the following resin intermediate prepared and which polymer is formed by this monomer unit?
ncert-exemplar-problems-class-12-chemistry-polymers-21

Q 30.

Which of the following polymer is biodegradable?
ncert-exemplar-problems-class-12-chemistry-polymers-2
ncert-exemplar-problems-class-12-chemistry-polymers-3

Q 31.

Match the polymers given in Column I with their main applications given in Column II.
ncert-exemplar-problems-class-12-chemistry-polymers-28

Q 32.

Is  (-NH — CHR—CO-)n a homopolymer or copolymer?

Q 33.

Assertion (A): For making rubber synthetically, isoprene molecules are polymerised.
i Reason (R): Neoprene (a polymer of chloroprene) is a synthetic rubber.

Q 34.

A natural linear polymer of 2-methyl-l,3-butadiene becomes hard on treatment with sulphur between 373 to 415 K and -S – S – bonds are formed between chains. Write the structure of the product of this treatment?

Q 35.

Which of the following are addition polymers?
(a) Nylon (b) Melamine formaldehyde resin
(c) Orion (d) Polystyrene

Q 36.

Can enzyme be called a polymer?

Q 37.

Match the polymers of Column I with correct monomers of Column II.
ncert-exemplar-problems-class-12-chemistry-polymers-25

Q 38.

Differentiate between rubbers and plastics on the basis of intermolecular forces.

Q 39.

Why should the monomers used in addition polymerisation through free radical pathway be very pure?

Q 40.

Low density polythene and high density polythene, both are polymers of ethane but there is marked difference in their properties. Explain.

Q 41.

What are the monomeric repeating units of Nylon-6 and Nylon 6,6?

Q 42.

Identify the type of polymer.
-A-A-A-A-A-A-

Q 43.

Which type of biomolecules have some structural similarity with synthetic polyamides? What is this similarity?

Q 44.

Match the polymers given in Column I with the type of linkage present in them given in Column II.
ncert-exemplar-problems-class-12-chemistry-polymers-30

Q 45.

Match the polymers given in Column I with their main applications given in Column II.
ncert-exemplar-problems-class-12-chemistry-polymers-29

Q 46.

In the following questions, a statement of Assertion (A) followed by a statement of
Reason (R) is given. Choose the correct answer out of the following choices:
(a) Assertion and Reason both are correct statements but Reason is not the correct explanation of Assertion.
(b) Assertion and Reason both are correct statements and Reason is the correct explanation of Assertion.
(c) Both Assertion and Reason are false.
(d) Assertion is correct but Reason is false.
(e) Assertion is false but Reason is correct.

Assertion (A): Rayon is a semi-synthetic polymer and is taken as a better choice than cotton fabric.
Reason (R): Mechanical and aesthetic properties of cellulose can be improved by acetylation.

Q 47.

Arrange the following polymers in increasing order of their intermolecuiar forces.
(i) Nylon 6,6, Buna-S, Polythene
(ii) Nylon 6, Neoprene, Polyvinyl chloride

Q 48.

What are natural and synthetic polymers? Give two examples of each type.

Q 49.

Define thermoplastics and thermo setting polymers with two examples of each

Q 50.

How is dacron obtained from ethylene glycol and terephthalic acid?