Chemistry

Polymers

Question:

Identify the type of polymer given in the following figure.
ncert-exemplar-problems-class-12-chemistry-polymers-19

Answer:

It is a cross linked polymer, since the various polymer chains are joined together to form a three-dimensional network structure (giant molecule).

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Polymers

Q 1.

Which of the following polymers are used as fibre?
(a) Polytetrafluoroethane (b) Poly chloroprene
(c) Nylon (d) Terylene

Q 2.

Write the monomers used for gettingThe following polymers:
(i) Polyvinylchloride
(ii) Teflon (iii) Bakelite

Q 3.

Which of the following polymers soften on heating and harden on cooling? What are the polymers with this property collectively called? What are the polymers with this property collectively called? What are the structural similarities between such polymers? Bakelite, urea-formaldehyde resin, polythene, polyvinyl, polystyrene.

Q 4.

Which of the following polymers are condensation polymers?
(a) Bakelite (b) Teflon
(c) Butyl rubber (d) Melamine formaldehyde resin

Q 5.

Is  (-NH — CHR—CO-)n a homopolymer or copolymer?

Q 6.

Assertion (A): Olefinic monomers undergo addition polymerization.
Reason (R): Polymerisation of vinyl chloride is initiated by peroxides/ persulphates.

Q 8.

Out of chain growth polymerisation and step growth polymerisation, in which type will you place the following.
ncert-exemplar-problems-class-12-chemistry-polymers-18

Q 9.

Name the polymers used in laminated sheets and give the name of monomeric units involved in its formation.

Q 10.

Match materials given in Column I with the polymers given in Column II.
ncert-exemplar-problems-class-12-chemistry-polymers-31

Q 11.

What is a biodegradable polymer ? Give an example of a biodegradable aliphatic polyester.

Q 12.

In which of the following polymers ethylene glycol is one of the monomer units?
ncert-exemplar-problems-class-12-chemistry-polymers-5

Q 13.

Write the free radical mechanism for the polymerisation of ethene.

Q 14.

Which of the following polymers are thermoplastic?
(a) Teflon (b) Natural rubber (c) Neoprene (d) Polystyrene

Q 15.

Match the polymers given in Column I with their chemical names given in Column II.
ncert-exemplar-problems-class-12-chemistry-polymers-26

Q 16.

What are polymers?

Q 17.

Which of the following are characteristics of thermosetting polymers?
(a) Heavily branched cross linked polymers.
(b) Linear slightly branched long chain molecules.
(c) Become infusible on moulding so cannot be reused.
(d) Soften on heating and harden on cooling, can be reused.

Q 18.

Can nucleic acids, proteins and starch be considered as step growth polymers?

Q 19.

Discuss the main purpose of vulcanisation of rubber.

Q 20.

Write the names and structures of the monomers of the following polymers:
(i) Buna-S (ii) Buna-N (iii) Dacron (iv) Neoprene

Q 21.

What is the role of benzoyl peroxide in addition polymerization of alkenes? Explain its mode of action with the help of an example.

Q 22.

In which classes, the polymers are classified on the basis of molecular forces?

Q 23.

Identify the type of polymer given in the following figure.
ncert-exemplar-problems-class-12-chemistry-polymers-19

Q 24.

How are polymers classified on the basis of structure?

Q 25.

Assertion (A): Polyamides are best used as fibres because of high tensile strength.
Reason (R): Strong intermolecular forces (like hydrogen bonding within polyamides) lead to close packing of chains and increase the crystalline character, hence, provide high tensile strength to polymers.

Q 26.

Match the polymers given in Column I with their repeating units given in Column 11.
ncert-exemplar-problems-class-12-chemistry-polymers-32

Q 27.

How is the following resin intermediate prepared and which polymer is formed by this monomer unit?
ncert-exemplar-problems-class-12-chemistry-polymers-21

Q 28.

What is the structural difference between HDP and LDP? How does the structure account for different behaviour and nature, hence the use of a polymer?

Q 29.

Which of the following are examples of synthetic rubber?
(a) Polychloroprene (b) Polyacrylonitrile
(c) Buna-N (d) cis-polyisoprene

Q 30.

Which of the following polymer is biodegradable?
ncert-exemplar-problems-class-12-chemistry-polymers-2
ncert-exemplar-problems-class-12-chemistry-polymers-3

Q 31.

Which type of biomolecules have some structural similarity with synthetic polyamides? What is this similarity?

Q 32.

Assertion (A): For making rubber synthetically, isoprene molecules are polymerised.
i Reason (R): Neoprene (a polymer of chloroprene) is a synthetic rubber.

Q 33.

Which of the following monomers form biodegradable polymers?
(a) 3-hydroxybutanoic acid +3-hydroxypentanoic acid
(b) Glycine + aminocaproic acid  
(c) Ethylene glycol + phthalic acid
(d) Caprolactam

Q 34.

Assertion (A): For making rubber synthetically, isoprene molecules are polymerised.
i Reason (R): Neoprene (a polymer of chloroprene) is a synthetic rubber.

Q 35.

Which of the following are addition polymers?
(a) Nylon (b) Melamine formaldehyde resin
(c) Orion (d) Polystyrene

Q 36.

Vulcanisation makes rubber .
(a) more-elastic (b) soluble in inorganic solvent
(c) crystalline (d) more stiff

Q 37.

Match the polymers given in Column I with their main applications given in Column II.
ncert-exemplar-problems-class-12-chemistry-polymers-28

Q 38.

Why does cw-polyisoprene possess elastic property?

Q 39.

Assertion (A): Most of the synthetic polymers are not biodegradable.
Reason (R): Polymerisation process induces toxic character in organic molecules.

Q 40.

Classify the following as addition and condensation polymers:
Terylene, Bakelite, Polyvinyl chloride,Polythene

Q 41.

Identify the type of polymer.
-A-B-B-A-A-A-B-A-

Q 42.

Assertion (A): Network polymers are thermosetting.
Reason (R): Network polymers have high molecular mass.

Q 43.

Low density polythene and high density polythene, both are polymers of ethane but there is marked difference in their properties. Explain.

Q 44.

Explain the difference between Buna- N and Buna-S.

Q 45.

How do you explain the functionality of a monomer?

Q 46.

Define the term polymerisation?

Q 47.

What are the monomeric repeating units of Nylon-6 and Nylon 6,6?

Q 48.

Why should the monomers used in addition polymerisation through free radical pathway be very pure?

Q 49.

Match the polymers of Column I with correct monomers of Column II.
ncert-exemplar-problems-class-12-chemistry-polymers-25

Q 50.

Assertion (A): Olefinic monomers undergo addition polymerization.
Reason (R): Polymerisation of vinyl chloride is initiated by peroxides/ persulphates.