Describe a method for refining nickel.
When impure nickel is heated in presence of CO at 330-350 K, it forms volatile nickel tetracarbonyl leaving behind the impurities. The nickel tetracarbonyl thus obtained is then heated to higher temperature (450-470K), then it undergoes thermal decomposition to give pure nickel.
Assertion (A): Zirconium can be purified by van Arkel method.
Reason (R): ZrI4 is volatile and decomposes at 1800 K.
The main reactions occurring in blast furnace during extraction of iron from haematite are
t the temperature corresponding to which of the points in figure of Q. 11-13, FeO will be reduced to Fe by coupling the reaction 2FeO —> 2Fe + 02 with all of the following reactions?
Which of the following statements are correct about the role of substances added in the froth floatation process?
(a) Collectors enhance the non-wettability of the mineral particles.
(b) Collectors enhance the wettability of gangue particles.
(c) By using depressants in the process two sulphide ores can be separated.
(d) Froth stabilizers decrease wettability of gangue.
Is it true that under certain conditions, Mg can reduce Al203 and Al can reduce MgO? What are those conditions?
The value of ΔfG ° for formation of Cr2O3 is – 540 kJ mol-1 and that of Al203 is – 827 kJ mol-1 . Is the reduction of Cr2O3 possible with Al?
Wrought iron is the purest form of iron. Write a reaction used for the preparation of wrought iron from cast iron. How can the impurities of sulphur, silicon and phosphorus be removed from cast iron?
Why is the extraction of copper from pyrites more difficult than that from its oxide ore through reduction?
Extraction of gold and silver involves leaching the metal with CN+ ion. The metal is recovered by
(a) displacement of metal by some other metal from the complex ion
(b) roasting of metal complex
(c) calcinations followed by roasting
(d) thermal decomposition of metal complex
In the extraction of aluminium by Hall-Heroult process, purified A1203 is mixed with CaF2 to
(a) lower the melting point of A1203.
(b) increase the conductivity of molten mixture.
(c) reduce Al+3 into Al(s).
(d) acts as catalyst.
Assertion (A): Hydrometallurgy involves dissolving the ore in a suitable reagent followed by precipitation by a more electropositive metal.
Reason (R): Copper is extracted by hydrometallurgy.
Why is sulphide ore of copper heated in a furnace after mixing with silica? Iron oxide present as impurity in sulphide ore of copper forms a slag of iron silicate and copper is produced in the form of copper matte.
Name the common elements present in the anode mud in electrolytic refining of copper. Why are they so present?
What criterion is followed for the selection of the stationary phase in chromatography?
Name the processes from which chlorine is obtained as a by-product What will happen if an aqueous solution of NaCl is subjected to electrolysis?
For the reduction of FeO at the temperature corresponding to point D, which of the following statement is correct?
Assertion (A): Sulphide ores are concentrated by froth floatation method. Reason (R): Cresols stabilize the froth in froth floatation method.
The choice of a reducing agent in a particular case depends on thermodynamic factor. How far do you agree with this statement? Support your opinion with two examples.
For the metallurgical process of which of the ores, calcined ore can be reduced by carbon?
(a) Haematite (b) Calamine (c) Iron pyrites (d) Sphalerite
Why is an external emf of the more than 2.2 V required for the extraction of Cl2 from brine?
How are metals used as semiconductors refined? What is the principle of the method used?
Which of the following options are correct?
(a) Cast iron is obtained by remelting pig iron with scrap iron and coke using hot air blast.
(b) In extraction of silver, silver is extracted as cationic complex.
(c) Nickel is purified by zone refining.
(d) Zr and Ti are purified by van Arkel method.
In which of the following method of purification, metal is converted to its volatile compound which is decomposed to give pure metal?
(a) Heating with stream of carbon monoxide
(b) Heating with iodine
(c) Liquation
(d) Distillation
Which of the following statements are correct?
(a) A depressant prevents certain type of particle to come to the froth.
(b) Copper matte contains Cu2S and ZnS.
(c) The solidified copper obtained from reverberatory furnace has blistered appearance due to evolution of SO2 during the extraction.
(d) Zinc can be extracted by self-reduction.
