Chemistry

The s-Block Elements

Question:

Several sodium compounds find use in industries. Which of the following compounds are used for textile industry?
(a) Na2C03                        
(b) NaHC03                        
(c) NaOH                              
(d) NaCl

Answer:

(a, c) Na2C03 and NaOH are used in textile industry.

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The s-Block Elements

Q 1.

Name the compounds used for the manufacture of washing soda by Solvay process.

Q 2.

Name the alkali metal which shows diagonal relationship with magnesium?

Q 3.

What is Quick lime? What happens when it is added to water?

Q 4.

Lithium resembles magnesium in some of its properties. Mention two such properties and give reasons for this resemblance.

Q 5.

What happens when crystals of washing soda are exposed to air?

Q 6.

What is the effect of heat on the following compounds (Give equations for the reactions)?  (i) CaC03 (ii) CaSO4 2H2O

Q 7.

Which is more basic NaOH or Mg(OH)2?

Q 8.

Explain why is sodium less reactive than potassium.

Q 9.

What happens when sodium metal is heated in free supply of air?

Q 10.

How would you prepare sodium silicate from silica?

Q 11.

What is the general name for elements of group 1 ?

Q 12.

Which alkaline earth metals do not impart colour to the flame?

Q 13.

Why does the solution of alkali metals becomes blue in liquid ammonia? Give the chemical equation also.

Q 14.

Metals form basic hydroxides. Which of the following metal hydroxides is the least basic?
(a) Mg(OH)2 (b) Ca(OH)2                             (c) Sr(OH)2                           (d) Ba(OH)2

Q 15.

Match the elements given in Column I with the colour they impart to the flame given in Column II.

Column I Column II
(i) Cs (a) Apple green
(ii) Na (b) Violet
(iii) K (c) Brick red
(iv) Ca (d) Yellow
(v) Sr (e) Crimson red
(vi) Ba (f) Blue

 

Q 16.

Explain the significance of sodium, potassium, magnesium and calcium in biological fluids.

Q 17.

Why is the solution of alkali metals in liquid ammonia conducting in nature?

Q 18.

Alkali metals react with water vigorously to form hydroxides and dihydrogen. Which of the following alkali metals reacts with water least vigorously?
(a) Li . (b) Na (c) K (d) Cs

Q 19.

When sodium is dissolved in liquid ammonia, a solution of deep blue colour is obtained. The colour of the solution is due to
(a) ammoniated electron                                          
(b) sodium ion
(c) sodium amide                                                                      
(d) ammoniated sodium ion

Q 20.

Beryllium and magnesium do not give colour to flame whereas other alkaline earth metals do so. Why?

Q 21.

What happens when
(i) Sodium metal is dropped in water?
(ii) Sodium metal is heated in free supply of air?
(iii) Sodium peroxide dissolves in water?

Q 22.

Why are alkali metals soft?

Q 23.

Why are alkali metals always univalent? Which alkali metal ion forms largest hydrated ion in aqueous solution?

Q 24.

Which of the carbonates given below is unstable in air and is kept in C02 atmosphere to avoid decomposition.
(a) BeCO3
(b) MgC03
(c) CaC03
(d) BaCO3

Q 25.

In the Solvay process, can we obtain sodium carbonate directly by treating the solution containing (NH4)2C03 with sodium chloride? Explain.

Q 26.

Match the elements given in Column I with the properties mentioned in Column II.

Column I Column II
(i) Li (a) Insoluble sulphate
(ii) Na (b) Strongest monoacidic base
(iii) Ca (c) Most negative E ° value among alkali metals
(iv) Ba (d) Insoluble oxalate                                                                         ‘
  (e) 6s2 outer electronic configuration

 

Q 27.

Starting with sodium chloride how would you proceed to prepare.
(i) Sodium metal (ii) Sodium hydroxide
(iii) Sodium peroxide (iv) Sodium carbonate?

Q 28.

Draw the structure of (i) BeCl2 (vapour), (ii) BeCl2 (solid).

Q 29.

Some of the Group 2 metal halides are covalent and soluble in organic solvents. Among the following metal halides, the one which is soluble in ethanol is
(a) BeCl2
(b) MgCl2                                    
(c) CaCl2                                
(d) SrCl2

Q 30.

The order of decreasing ionization enthalpy in alkali metals is

(a) Na > Li > K > Rb (b) Rb < Na < K < Li

(c) Li > Na > K > Rb (d) K < Li < Na < Rb

Q 31.

Which of the following compounds are readily soluble in water?
(a) BeS04                            
(b) MgS04                            
(c) BaS04                                
(d) SrS04

Q 32.

Identify the correct’ formula of halides of alkaline earth metals from the following.
(a) BaCl2.2H20
(b) BaCl2  .4H20
(c) CaCl2 . 6H20
(d) SrCl2.4H20

Q 33.

Compare the alkali metals and alkaline earth metals with respect to (i) ionization enthalpy, (ii) basicity of oxides, (iii) solubility of hydroxides.

Q 34.

Describe two important uses of each of the following: ,
(i) caustic soda (ii) sodium carbonate (iii) quick lime

Q 35.

Describe the importance of the following:
(i) Limestone (ii) Cement (iii) Plaster of Paris.

Q 36.

State as to why
(a) Alkali metals show only +1 oxidation state. (b) Na and K impart colour to the flame but Mg does not.(c) Lithium on being heated in air mainly forms the monoxide and not the peroxide.(d) Li is the best reducing agent in aqueous solution.

Q 37.

By adding gypsum to cement
(a) setting time of cement becomes less.
(b) setting time of cement increases.
(c) colour of cement becomes light.
(d) shining surface is obtained.

Q 38.

How do you account for the strong reducing power of lithium in aqueous  solution? .

Q 39.

Discuss the trend of the following:
(i) Thermal stability of carbonates of Group 2 elements.
(ii) The solubility and the nature of oxides, of Group 2 elements.

Q 40.

Potassium carbonate cannot be prepared by Solvay process. Why?

Q 41.

Why are lithium salts commonly hydrated and those of the other alkali metal ions usually anhydrous?

Q 42.

Comment on each of the following observations:
(a) The mobilities of the alkali metal ions in aqueous solution are Li+ < Na+ + < Rb+ < Cs+
(b) Lithium is the only alkali metal to form a nitride directly.
(c) Ee for M2+  (aq) + 2e —> M(s) (where M = Ca, Sr, or Ba) is nearly constant.

Q 43.

Which of the alkali metal is having least melting point?
(a) Na (b) K (c) Rb (d) Cs

Q 44.

Which one of the following alkaline earth metal carbonates is thermally most stable?
(a) MgCO3 (b) CaCO3 (c) SrCO3 (d) BaCO3

Q 45.

Name the alkaline earth metals whose salt do not impart colour to a non-luminous flame.

Q 46.

Arrange the following in the increasing order of solubility in water.
 MgCl2, CaCl2, SrCl2, BaCl2

Q 47.

Why do alkali metals give characteristic flame colouration?

Q 48.

What is soda ash?

Q 49.

Which out of the following can be used to store an alkali metal?
H2O, C2H5OH and Benzene

Q 50.

Potassium carbonate cannot be prepared by Solvay process. Why?