Covalent bonds can undergo fission in two different ways. The correct representation involving the heterolytic fission of CH3 – Br is
(b) Arrow denotes the direction of movement of electrons
Since, Br is more electronegative than carbon, hence heterolytic fission occurs in such a way that CH3 gets the positive charge and Br gets the negative charge. Thus, option (b) is correct.
Classify the following reactions in one of the reaction type studied in this unit.
(a) CH3CH2Br + HS– ———–> CH3CH2SH + Br–
(b) (CH3)2C=CH2 + HCl ———–> (CH3)2CCl—CH3
(c) CH3CH2Br + HO– ———–> CH2=CH2 + H2O + Br–
(d) (CH3)3C—CH2OH + HBr ———–> (CH3)2 C Br CH2CH2CH3 + H2O
By mistake, an alcohol (boiling point 97 °C) was mixed with a hydrocarbon (boiling point 68 °C). Suggest a suitable method to separate the two compounds. Explain the reason for your choice.
(a) 1 -Chloro-2-nitro-4-methylbenzene
(b) l-Chloro-4-methyl-2-nitrobenzene
(c) 2-Chloro-1 -nitro-5-methylbenzene
(d) m-Nitro-p-chlorotoluene
Name a suitable technique of separation of the components from a mixture of calcium sulphate and camphor.
The IUPAC name for
(a) 1-Hydroxypentane-l, 4-dione
(b) 1,4-Dioxopentanol
(c) l-Carboxybutan-3-one
(d) 4-Oxopentanoic acid
Electronegativity of carbon atoms depends upon their state of hybridization. In which of the following compounds, the carbon marked with asterisk is most electronegative?
Describe the method, which can be used to separate two compounds with different solubilities in a solvent S.
Will CCl4 give white precipitate of AgCl on heating it with silver nitrate? Give reason for your answer.
What are electrophiles? Explain electrophile substitution reaction with the help of example.
(a) 2-Ethyl-3-methylpentane
(b) 3,4-Dimethylhexane
(c) 2-sec-Butylbutane
(d) 2,3-Dimethylbutane
In DNA and RNA, nitrogen atom is present in the ring system. Can Kjeldahl method be used for the estimation of nitrogen present in these? Give reasons.
In the Lassaigne’s test for ntrogen in an organic compound, the Prussian blue colour is obtaine d due to the formation of:
(a) Na4[Fe(CN)6] (b)Fe4[Fe(CN)6]3
(c) Fe2[Fe(CN)6] (d)Fe3[Fe(CN)6]4 .
0.15 g of an organic compound gave 0.12 g of Ag Br by the Carius method. Find percentage of Br in the compound.
In which of the following compounds the carbon marked with asterisk is expected to have greatest positive charge?
Two or more compounds having same the molecular formula but different functional groups are called functional isomers. Which of die following pairs are not functional group isomers?
(a) II and III (b) II and IV
(c) I and IV (d) I and II
Which of the following compounds will not exist as resonance hybrid? Give reason for your answer.
(a) CH3OH
(b) R-CONH2
(c) CH3CH = CHCH2NH2
Discuss the principle of estimation of halogens, sulphur and phosphorus present in an organic compound.
(a) Which is more suitable method for the purification of a compound in liquid state which decomposes at or below its boiling point?
(b) How will you separate a mixture of ammonium chloride and common salt?
Explain hyperconjugation effect. How does hyperconjugation effect explain the stability ofalkenes ?
Why is it necessary to use acetic acid and not sulphric acid for acidification of sodium extract for testing sulphur by lead acetate test?
(a) What is the basic principle involved in the estimation of nitrogen by Dumas method.
(b) In a Dumas nitrogen estimation method, 0.30 g of an organic compound gave 50 cm3 of N2 collected at 300 K and 715 mm Hg pressure. Calculate the percentage composition of nitrogen in the compound. (Vapour pressure of water at 300 K is 15 mm Hg)
Covalent bonds can undergo fission in two different ways. The correct representation involving the heterolytic fission of CH3 – Br is
Which of the following compounds contain all the carbon atoms in the same hybridization state?
Compounds with same molecular formula but differing in their structures are said to be structural isomers. What type of structural isomerism is shown by
The structure of triphenylmethyl cation is given here. This is very stable and some of its salts can be stored for months. Explain the cause of high stability of this cation
Resonance structures of propenal are given below. Which of these resonating structures is more stable? Give reason for your answer.
What are hybridisation states of each carbon atom in the following compounds? CH2=C=O, CH3CH=CH2, (CH3)2CO, CH2=CHCN, C6H6.
Draw formulas for the first five members of each homologous series beginning with the following compounds,
(a) H—COOH (b) CH3COCH3 (c) H—CH=CH2
Suggest a suitable technique for separating naphthalene from kerosene oil present in a mixture.
Write the name of element which is confirmed on adding Na2[Fe(CN)5NO] in sodium extract solution due to appearance of violet colouration.
