The intermediate carbocation formed in the reactions of HI, HBr and HC1 with propene is the same and the bond energy of HCl, HBr and HI is 430.5 kJ mol-1,363.7 kJ mol–1 and 296.8 kJ mol-1 What will be the other of reactivity of these halogen acids?
The bond dissociation enthalpy decreases in the order HC1 > HBr > HI, therefore, the order of reactivity is in the reverse order i.e., HI > HBr > HCl.
In the alkane, CH3CH2—C(CH3)2—CH2—CH(CH3)2, identify 1 °, 2 °, 3 ° carbon atoms and give the number of H-atoms bonded to each one of these.
Nucleophiles and electrophiles are reaction intermediates having electron rich and electron deficient centres respectively. Hence, they tend to attack electron deficient and electron rich centres respectively. Classify the following species as electrophiles and nucleophiles.
Out of benzene, m-dinitrobenzene and toluene which will undergo nitration most easily and why?
For the following compounds, write structural formulas and IUPAC names for all possible isomers having the number of double or triple bond as indicated:
(a) C4H8 (one double bond) (b) C5H8 (one triple bond)
The relative reactivity of 1 °, 2 ° and 3 ° hydrogens towards chlorination is 1: 3.8 : 5. Calculate the percentages of all monochlorinated products obtained from 2-methylbutane.
Which of the following are correct?
(a) CH3 – O – CH+2 is more stable than CH3 – CH+2
(b) (CH3)2CH+ is less stable than CH3 – CH2 – CH+2
(c) CH2 = CH – CH+2 is more stable than CH3 – CH2 – CH+2
(d) CH2 = CH+ is more stable than CH3 – CH+2
The molecules having dipole moment are________ .
(a) 2,2-Dimethylpropane
(b) trans-Pent-2-ene
(c) cw-Hex-3-ene
(d) 2,2,3,3-Tetramethylbutane
Arrange the following: HCl, HBr, HI, HF in order of decreasing reactivity towards alkenes.
Write the IUPAC names of the following compounds.
(i) (CH3)CCH2C(CH3)3 (ii) (CH3)2C(C2H5)2
(a) Why are alkenes called unsaturated hydrocarbons?
(b) How will you test the presence of double bond in an alkene?
(c) Name the products formed when propene is subjected to ozonolysis.
Explain the term aromaticity. What are the necessary conditions for any compound to show aromaticity?
In an electrophilic substitution reaction of nitrobenzene, the presence of nitro group ________ ‘
(a) deactivates the ring by inductive effect
(b) activates the ring by inductive effect
(c) decreases the charge density at ortho- and para-positions of the ring relative to meta-position by resonance
(d) increases the charge density at meta-position relative to the ortho and para-positions of the ring by resonance
Propanal and pentan-3-ene are the ozonolysis products of an alkene. What is the structural formula of the alkene?
An alkene ‘A’ on ozonolysis gives a mixture of ethanal and pentan-3-one. Write the structure and IUPAC name of ‘A’.
Discuss the preparation of alkanes by Wurtz reaction. What is the limitaHon of the reaction?
How will you demonstrate that double bonds of benzene are somewhat different from that of olefins?
Rotation around carbon-carbon single bond of ethane is not completely free. Justify the statement.
Draw the cis- and trans-structures for hex-2-ene. Which iosmer will have higher b.p. and why?
Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?
Suggest the name of another Lewis acid instead of anhydrous aluminium chloride which can be used during ethylation of benzene.
What happens when benzene is treated with excess of Cl2 in presence of sunlight? Give chemical reaction.
An alkene ‘A’ contains three C-C, eight C-H σ bonds and one C-C Ï€ bond. ‘A' on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Deduce IUPAC name of’A’.
For an electrophilic substitution reaction, the presence of a halogen atom in the benzene ring ;
(a) deactivates the ring by inductive effect
(b) deactivates the ring by resonance
(c) increases the charge density at ortho and para-positions relative to meta-position by resonance
(d) directs the incoming electrophile to meta-position by increasing the
charge density relative to ortho and para-positions. ‘
Why does the presence of a nitro group-make the benzene ring less reactive in comparison to the unsubstituted benzene ring? Explain.
Arrange benzene, n-hexane and ethyne in decreasing order of acidic behaviour. Also give reason for this behaviour.
