Discuss the preparation of alkanes by Wurtz reaction. What is the limitaHon of the reaction?
Wurtz synthesis: Higher alkanes are prepared by heating an alkyl halide (RX) with sodium metal in dry ether solution.
Limitations: Use of two different alkyl halides in Wurtz reaction always leads to a mixture of alkanes. The separation of these alkanes is difficult because there is only a little difference in their boiling points. Thus only symmetrical alkanes can be prepared by this method.
In the alkane, CH3CH2—C(CH3)2—CH2—CH(CH3)2, identify 1 °, 2 °, 3 ° carbon atoms and give the number of H-atoms bonded to each one of these.
Nucleophiles and electrophiles are reaction intermediates having electron rich and electron deficient centres respectively. Hence, they tend to attack electron deficient and electron rich centres respectively. Classify the following species as electrophiles and nucleophiles.
The relative reactivity of 1 °, 2 ° and 3 ° hydrogens towards chlorination is 1: 3.8 : 5. Calculate the percentages of all monochlorinated products obtained from 2-methylbutane.
For the following compounds, write structural formulas and IUPAC names for all possible isomers having the number of double or triple bond as indicated:
(a) C4H8 (one double bond) (b) C5H8 (one triple bond)
Which of the following are correct?
(a) CH3 – O – CH+2 is more stable than CH3 – CH+2
(b) (CH3)2CH+ is less stable than CH3 – CH2 – CH+2
(c) CH2 = CH – CH+2 is more stable than CH3 – CH2 – CH+2
(d) CH2 = CH+ is more stable than CH3 – CH+2
Out of benzene, m-dinitrobenzene and toluene which will undergo nitration most easily and why?
The molecules having dipole moment are________ .
(a) 2,2-Dimethylpropane
(b) trans-Pent-2-ene
(c) cw-Hex-3-ene
(d) 2,2,3,3-Tetramethylbutane
Write the IUPAC names of the following compounds.
(i) (CH3)CCH2C(CH3)3 (ii) (CH3)2C(C2H5)2
Arrange the following: HCl, HBr, HI, HF in order of decreasing reactivity towards alkenes.
Explain the term aromaticity. What are the necessary conditions for any compound to show aromaticity?
How will you demonstrate that double bonds of benzene are somewhat different from that of olefins?
An alkene ‘A’ on ozonolysis gives a mixture of ethanal and pentan-3-one. Write the structure and IUPAC name of ‘A’.
Draw the cis- and trans-structures for hex-2-ene. Which iosmer will have higher b.p. and why?
Suggest the name of another Lewis acid instead of anhydrous aluminium chloride which can be used during ethylation of benzene.
Draw Newman and Sawhorse projections for the eclipsed and staggered conformations of ethane. Which of these conformations is more stable and why? .
Propanal and pentan-3-ene are the ozonolysis products of an alkene. What is the structural formula of the alkene?
(a) Why are alkenes called unsaturated hydrocarbons?
(b) How will you test the presence of double bond in an alkene?
(c) Name the products formed when propene is subjected to ozonolysis.
For an electrophilic substitution reaction, the presence of a halogen atom in the benzene ring ;
(a) deactivates the ring by inductive effect
(b) deactivates the ring by resonance
(c) increases the charge density at ortho and para-positions relative to meta-position by resonance
(d) directs the incoming electrophile to meta-position by increasing the
charge density relative to ortho and para-positions. ‘
In an electrophilic substitution reaction of nitrobenzene, the presence of nitro group ________ ‘
(a) deactivates the ring by inductive effect
(b) activates the ring by inductive effect
(c) decreases the charge density at ortho- and para-positions of the ring relative to meta-position by resonance
(d) increases the charge density at meta-position relative to the ortho and para-positions of the ring by resonance
Alkynes on reduction with sodium in liquid ammonia form trans alkenes. Will butene formed on the reduction of but-2-yne show geometrical isomerism?
An alkene ‘A’ contains three C—C, eight C—H, a-bonds, and one C—C n-bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write the IUPAC name of’A’.
Write down the products ofozonolysis ofl, 2-dimethylbenzene (o-xylene). How does the result support Kekule structure of benzene?
What happens when benzene is treated with excess of Cl2 in presence of sunlight? Give chemical reaction.
An alkene ‘A’ contains three C-C, eight C-H σ bonds and one C-C Ï€ bond. ‘A' on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Deduce IUPAC name of’A’.
Which are the correct IUPAC names of the following compound
(a) 5-(2′,2′-Dimethylpropyl)decane
(b) 4-Butyl-2,2-dimethylnonane
(c) 2,2-Dimethyl-4-pentyloctane
(d) 5-neo-Pentyldecane
The intermediate carbocation formed in the reactions of HI, HBr and HC1 with propene is the same and the bond energy of HCl, HBr and HI is 430.5 kJ mol-1,363.7 kJ mol–1 and 296.8 kJ mol-1 What will be the other of reactivity of these halogen acids?
