The first ionisation enthalpy of magnesium is higher than that of sodium. On the other hand, the second ionisation enthalpy of sodium is very much higher than that of magnesium. Explain.
The 1st ionisation enthalpy of magnesium is higher than that of Na due to higher nuclear charge and slightly smaller atomic radius of Mg than Na. After the loss of first electron, Na+ formed has the electronic configuration of neon (2, 8). The higher stability of the completely filled noble gas configuration leads to very high second ionisation enthalpy for sodium. On the other hand, Ma+ formed after losing first electron still has one more electron in its outermost (3s) orbital. As a result, the second ionisation enthalpy of magnesium is much smaller than that of sodium.
Give reasons:
(i) IE1 of sodium is lower than that of magnesium whereas IE2 of sodium is higher than that of magnesium.
(ii) Noble gases have positive value of electron gain enthalpy.
All transition elements are d-block elements, but all d-block elements are not transition elements. Explain.
Discuss and compare the trend in ionization enthalpy of the elements of group 1 with those of group 17 elements.
Use periodic table to answer the following questions:
(a) Identify the element with five electrons in the outer subshell.
(b) Identify the element that would tend to lose two electrons.
(c) Identify the element that would tend to gain two electrons.
How would you react to the statement that the electronegativity ofN on Pauling scale is 3.0 in all the nitrogen compounds?
Which of the following have no unit?
(a) Electronegativity (b) Electron gain enthalpy
(c) Ionisation enthalpy (d) Metallic character
p-Block elements form acidic, basic and amphoteric oxides. Explain each property by giving two examples and also write the reactions of these oxides with water.
Explain why chlorine can be converted into chloride ion more easily as compared to fluoride ion from fluorine ?
Show by a chemical reaction with water that Na20 is a basic oxide and Cl207 is an acidic oxide.
Elements A, B, C and D Iwoe atomic numbers 12,19, 29, and 36 respectively. On the basis of electronic configuration, write to which group of the periodic table each element belongs.
Those elements impart colour to the flame on heating in it, the atoms of which require low energy for the ionization (i.e., absorb energy in the visible region of spectrum). The elements of which of the following groups will impart colour to the flame?
(a) 2 (b) 13 (c) 1 (d) 17
Which of the following sequences contain atomic numbers of only representative elements?
(a) 3, 33, 53, 87
(b) 2, 10, 22, 36
(c) 7, 17,25,37,48
(d) 9,35,51,88
Which important property did Mendeleev use to classify the elements in this periodic table and did he stick to that?
On the basis of quantum numbers, justify that the sixth period of the periodic table should have 32 elements.
Would you expect the first ionization enthalpies of two isotopes of the same element to be the same or different? Justify your answer.
Define the term ionization enthalpy? How does it vary along a period and along a group?
The first ionization enthalpies of Na, Mg, A1 and Si are in the order
(a) Na < Mg > A1 < Si
(b) Na>Mg>Al>Si
(c) Na < Mg < A1 < Si
(d) Na > Mg > A1 < Si
The formation of the oxide ion, 02-(g), from oxygen atom requires first an exothermic and then an endothermic step as shown below:
O(g) + e–→0– (g), ∆H= -141 kJ mol-1
0–(g) + e–→O2 (g), ∆H = +780 kJ mol-1
Thus process of formation of O2- ion in gas phase is unfavourable even though O2- is isoelectronic with neon. It is due to the fact that
(a) Oxygen is more electronegative.
(b) Addition of electron in oxygen results in larger size of the ion.
(c) Electron repulsion outweighs the stability gained by achieving noble gas configuration.
(d) 0– ion has comparatively smaller size than oxygen atom.
Which of the following sets contain only isoelectronic ions?
(a) Zn2+, Ca2+, Ga3+, Al3+
(b) K+, Ca2+, Sc3+, Cl–
(c) P3-, S2- Cl–,K+
(d) Ti4+, Ar, Cl3+, V5+
Nitrogen has positive electron gain enthalpy whereas oxygen has negative. However, oxygen has lower ionization enthalpy than nitrogen explain.
Match the correct atomic radius with the element.
| Column I (Element) | Column II (Atomic radius (pm) |
| Be | 74 |
| C | 88 |
| 0 | 111 |
| B | 77 |
| N | 66 |
Write down the outermost electronic configuration of alkali metals. How will you justify their placement in group 1 of the periodic table?
In what manner is the long form of periodic table better than Mendeleev's
periodic table? Explain with examples.
What is basic difference between the terms electron gain enthalpy and electro negativity?
Which of the above elements is likely to be:
(a) the least reactive element (b) the most reactive metal
(c) the most reactive non-metal (d) the least reactive non-metal
(e) the metal which can form a stable binary halide of the formula MX2(X = halogen)
(f) the metal which can form a predominantly stable covalent halide of the formula MX (X = halogen)?
Consider the isoelectronic species, Na+, Mg2+, F and O2-. The correct order of increasing length of their radii is
How would you explain the fact that first ionization enthalpy of sodium is lower than that of magnesium but its second ionization enthalpy is higher than that of magnesium?
Define ionization enthalpy. Discuss the factors affecting ionisation enthalpy of the elements and its trends in the periodic table.
Consider the following species:
N3-, O2-, F–, Na+, Mg2+, Al3+
(a) What is common in them?
(b) Arrange them in order of increasing ionic radii?
Energy of an electron in the ground state of the hydrogen atom is- 2.18 x 10-18 J.Calculate the ionization enthalpy of atomic hydrogen in terms of JMol-1.[Hint: Apply the idea of mole concept to derive the answer],
How would you explain the fact that the first ionization enthalpy of sodium is lower than that of magnesium but its second ionization enthalpy is higher than that of magnesium?
Would you expect the second electron gain enthalpy of O as positive, more negative or less negative than the first? Justify your answer.
The electronic configuration of an element is Is 2s 2p 3s 3p 4s . Locate the element in the periodic table.
Discuss the main characteristics of four blocks of elements in the periodic table? Give their general electronic configuration.
Discuss the factors that influence the magnitude of ionization enthalpy. What are the general trends of variation of ionization enthalpy in the periodic table? Explain.
Ionisation enthalpies of elements of second period are given below:
Ionisation enthalpy/kJ mol-1: 520, 899, 801, 1086, 1402, 1314, 1681, 2080. Match the correct enthalpy with the elements and complete the graph given in figure. Also write symbols of elements with their atomic number.
Illustrate by taking examples of transition elements and non-transition elements that oxidation states of elements are largely based on electronic configuration.
Arrange the elements N, P, O and S in the order of
(i) increasing first ionisation enthalpy.
(ii) increasing non-metallic character.
Give reason for the arrangement assigned.
Justify the given statement with suitable examples "the properties of the elements are a periodic function of their atomic numbers".
