Why is benzene extra-ordinarily stable though it contains three double bonds?
The six electrons of the p-orbitals cover all the six carbon atoms, and are said to be delocalized. As a result of delocalization there formed a stronger n-bond and a more stable molecule.
In the alkane, CH3CH2—C(CH3)2—CH2—CH(CH3)2, identify 1 °, 2 °, 3 ° carbon atoms and give the number of H-atoms bonded to each one of these.
Nucleophiles and electrophiles are reaction intermediates having electron rich and electron deficient centres respectively. Hence, they tend to attack electron deficient and electron rich centres respectively. Classify the following species as electrophiles and nucleophiles.
Out of benzene, m-dinitrobenzene and toluene which will undergo nitration most easily and why?
Which of the following are correct?
(a) CH3 – O – CH+2 is more stable than CH3 – CH+2
(b) (CH3)2CH+ is less stable than CH3 – CH2 – CH+2
(c) CH2 = CH – CH+2 is more stable than CH3 – CH2 – CH+2
(d) CH2 = CH+ is more stable than CH3 – CH+2
The molecules having dipole moment are________ .
(a) 2,2-Dimethylpropane
(b) trans-Pent-2-ene
(c) cw-Hex-3-ene
(d) 2,2,3,3-Tetramethylbutane
For the following compounds, write structural formulas and IUPAC names for all possible isomers having the number of double or triple bond as indicated:
(a) C4H8 (one double bond) (b) C5H8 (one triple bond)
Arrange the following: HCl, HBr, HI, HF in order of decreasing reactivity towards alkenes.
Write the IUPAC names of the following compounds.
(i) (CH3)CCH2C(CH3)3 (ii) (CH3)2C(C2H5)2
Arrange the following set of compounds in order of their decreasing relative reactivity with an electrophile, E+.
(a) Chlorobenzene, 2, 4-dinitrochlorobenzene, p-nitrochlorobenzene
(b) Toluene,p—H3C—C6H4—NO2, p—O2N—C6H4—NO2.
The relative reactivity of 1 °, 2 ° and 3 ° hydrogens towards chlorination is 1: 3.8 : 5. Calculate the percentages of all monochlorinated products obtained from 2-methylbutane.
How will you demonstrate that double bonds of benzene are somewhat different from that of olefins?
Classify the following compounds into (i) alkanes (ii) alkenes (iii) alkynes (iv) arenes. (a) C6H6 (b) C4H8 (C) C8H8 (d) C5H8 (e) C6H14
(a) Why are alkenes called unsaturated hydrocarbons?
(b) How will you test the presence of double bond in an alkene?
(c) Name the products formed when propene is subjected to ozonolysis.
Write chemical equations for the combustion reaction of the following hydrocarbons, (i) Butane (ii) Pentene (iii) Hexyne (iv) Toluene
(a) Define substitution reactions. Why do benzene undergo substitution reactions even though they contain double bonds?
(b) What happens when benzene is treated with
(i) Br2 in presence of anhydrous AlCl3
(ii) Cone. H2SO4 at 330K
(iii) Mixture of cone. H2SO4and com. HNO3 at 330 K
(iv) Ethanoyl Chloride in presence of anhydrous AlCl3
In an electrophilic substitution reaction of nitrobenzene, the presence of nitro group ________ ‘
(a) deactivates the ring by inductive effect
(b) activates the ring by inductive effect
(c) decreases the charge density at ortho- and para-positions of the ring relative to meta-position by resonance
(d) increases the charge density at meta-position relative to the ortho and para-positions of the ring by resonance
An alkene ‘A’ contains three C—C, eight C—H, a-bonds, and one C—C n-bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write the IUPAC name of’A’.
Arrange benzene, n-hexane and ethyne in decreasing order of acidic behaviour. Also give reason for this behaviour.
Arrange the following alkyl halides in decreasing order of the rate of β -elimination reaction with alcoholic KOH.
Arrange the following set of compounds in the order of their decreasing . relative reactivity with an electrophile. Give reason.
Why does the presence of a nitro group-make the benzene ring less reactive in comparison to the unsubstituted benzene ring? Explain.
Write down the products ofozonolysis ofl, 2-dimethylbenzene (o-xylene). How does the result support Kekule structure of benzene?
(a) What effect the branching of an alkane has on its melting point?
(b) Which of the following has highest boiling point?
(i) 2-methyl pentane
(ii) 2, 3-diethyl butane
(iii) 2, 2-dimethyl butane
Write the structure of the alkene which on reductive ozonolysis gives butanone and ethanol.
Discuss the preparation of alkanes by Wurtz reaction. What is the limitaHon of the reaction?
