Chemistry

Polymers

Question:

Why are rubbers called elastomers?

Answer:

Rubbers are stretched on application of force and come to its original position after the force is removed. Therefore, these are called elastomers.

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Polymers

Q 1.

Name the polymers used in laminated sheets and give the name of monomeric units involved in its formation.

Q 2.

Out of chain growth polymerisation and step growth polymerisation, in which type will you place the following.
ncert-exemplar-problems-class-12-chemistry-polymers-18

Q 3.

Write the monomers used for gettingThe following polymers:
(i) Polyvinylchloride
(ii) Teflon (iii) Bakelite

Q 4.

Which of the following polymers soften on heating and harden on cooling? What are the polymers with this property collectively called? What are the polymers with this property collectively called? What are the structural similarities between such polymers? Bakelite, urea-formaldehyde resin, polythene, polyvinyl, polystyrene.

Q 5.

Identify the type of polymer given in the following figure.
ncert-exemplar-problems-class-12-chemistry-polymers-19

Q 6.

Match materials given in Column I with the polymers given in Column II.
ncert-exemplar-problems-class-12-chemistry-polymers-31

Q 7.

Which of the following polymers are used as fibre?
(a) Polytetrafluoroethane (b) Poly chloroprene
(c) Nylon (d) Terylene

Q 8.

Which of the following are characteristics of thermosetting polymers?
(a) Heavily branched cross linked polymers.
(b) Linear slightly branched long chain molecules.
(c) Become infusible on moulding so cannot be reused.
(d) Soften on heating and harden on cooling, can be reused.

Q 10.

In which classes, the polymers are classified on the basis of molecular forces?

Q 11.

Write the free radical mechanism for the polymerisation of ethene.

Q 12.

Match the polymers given in Column I with their chemical names given in Column II.
ncert-exemplar-problems-class-12-chemistry-polymers-26

Q 13.

In which of the following polymers ethylene glycol is one of the monomer units?
ncert-exemplar-problems-class-12-chemistry-polymers-5

Q 14.

Assertion (A): Olefinic monomers undergo addition polymerization.
Reason (R): Polymerisation of vinyl chloride is initiated by peroxides/ persulphates.

Q 15.

What is the role of benzoyl peroxide in addition polymerization of alkenes? Explain its mode of action with the help of an example.

Q 16.

Which of the following monomers form biodegradable polymers?
(a) 3-hydroxybutanoic acid +3-hydroxypentanoic acid
(b) Glycine + aminocaproic acid  
(c) Ethylene glycol + phthalic acid
(d) Caprolactam

Q 17.

Which of the following polymers are thermoplastic?
(a) Teflon (b) Natural rubber (c) Neoprene (d) Polystyrene

Q 18.

Which of the following polymers are condensation polymers?
(a) Bakelite (b) Teflon
(c) Butyl rubber (d) Melamine formaldehyde resin

Q 19.

Assertion (A): Polyamides are best used as fibres because of high tensile strength.
Reason (R): Strong intermolecular forces (like hydrogen bonding within polyamides) lead to close packing of chains and increase the crystalline character, hence, provide high tensile strength to polymers.

Q 20.

What are polymers?

Q 21.

What is a biodegradable polymer ? Give an example of a biodegradable aliphatic polyester.

Q 22.

Write the names and structures of the monomers of the following polymers:
(i) Buna-S (ii) Buna-N (iii) Dacron (iv) Neoprene

Q 23.

Can nucleic acids, proteins and starch be considered as step growth polymers?

Q 24.

How are polymers classified on the basis of structure?

Q 25.

Assertion (A): For making rubber synthetically, isoprene molecules are polymerised.
i Reason (R): Neoprene (a polymer of chloroprene) is a synthetic rubber.

Q 26.

Match the polymers given in Column I with their main applications given in Column II.
ncert-exemplar-problems-class-12-chemistry-polymers-28

Q 27.

Which of the following polymer is biodegradable?
ncert-exemplar-problems-class-12-chemistry-polymers-2
ncert-exemplar-problems-class-12-chemistry-polymers-3

Q 28.

What is the structural difference between HDP and LDP? How does the structure account for different behaviour and nature, hence the use of a polymer?

Q 29.

Discuss the main purpose of vulcanisation of rubber.

Q 30.

Differentiate between rubbers and plastics on the basis of intermolecular forces.

Q 31.

Why should the monomers used in addition polymerisation through free radical pathway be very pure?

Q 32.

A natural linear polymer of 2-methyl-l,3-butadiene becomes hard on treatment with sulphur between 373 to 415 K and -S – S – bonds are formed between chains. Write the structure of the product of this treatment?

Q 33.

What is the structural difference between HDP and LDP? How does the structure account for different behaviour and nature, hence the use of a polymer?

Q 34.

Assertion (A): Olefinic monomers undergo addition polymerization.
Reason (R): Polymerisation of vinyl chloride is initiated by peroxides/ persulphates.

Q 35.

Which of the following are examples of synthetic rubber?
(a) Polychloroprene (b) Polyacrylonitrile
(c) Buna-N (d) cis-polyisoprene

Q 36.

To have practical applications why are cross links required in rubber?

Q 37.

Which type of biomolecules have some structural similarity with synthetic polyamides? What is this similarity?

Q 38.

Assertion (A): Network polymers are thermosetting.
Reason (R): Network polymers have high molecular mass.

Q 39.

Classify the following as addition and condensation polymers:
Terylene, Bakelite, Polyvinyl chloride,Polythene

Q 40.

Which of the following are addition polymers?
(a) Nylon (b) Melamine formaldehyde resin
(c) Orion (d) Polystyrene

Q 41.

Identify the type of polymer.
-A-B-B-A-A-A-B-A-

Q 42.

Can enzyme be called a polymer?

Q 43.

Why does cw-polyisoprene possess elastic property?

Q 44.

Assertion (A): Polytetrafluoroethene is used in making non-stick cookware. Reason (R): Fluorine has highest electronegativity.

Q 45.

Differentiate between rubbers and plastics on the basis of intermolecular forces.

Q 46.

Write the names of the monomers of the following polymers:
ncert-solutions-for-class-12-chemistry-polymers-1
ncert-solutions-for-class-12-chemistry-polymers-2

Q 47.

Is  (-NH — CHR—CO-)n a homopolymer or copolymer?

Q 48.

Which of the following polymer can be formed by using the following monomer unit?
ncert-exemplar-problems-class-12-chemistry-polymers-10

Q 49.

Which of the following polymers can have strong intermolecular forces?
(a) Nylon (b) Polystyrene (c) Rubber (d) Polyester

Q 50.

Which factor imparts crystalline nature to a polymer like nylon?