Distinguish between a sigma bond and a pi bond.
Match the species in Column I with the geometry/shape in Column II.
| Column I | Column II |
| (i) H30+ | (a) Linear |
| (ii) HC = CH | (b) Angular |
| (iii) Cl0–2 | (c) Tetrahedral |
| (iv) NH+4 | (d) Trigonal bipyramidal |
| – | (e) Pyramidal |
In N0–3 ion, the number of bond pairs and lone pairs of electrons on nitrogen atom are
(a) 2, 2 (b) 3, 1 (c) 1,3 (d) 4, 0
In which of the following substances will hydrogen bond be strongest?
(a) HCl
(b) H20
(c) HI
(d) H2S
Which of the following statements are correct about CO32- ?
(a) The hybridization of central atom is sp3.
(b) Its resonance structure has one C – O single bond and two C = O double bonds.
(c) The average formal charge on each oxygen atom is 0.67 units.
(d) All C – O bond lengths are equal.
Match the shape of molecules in Column I with the type of hybridization in Column II.
| Column I | Column II |
| (i) Tetrahedral | (a) sp2 |
| (ii) Trigonal | (b) sp |
| (iii) Linear | (c) sp3 |
The skeletal structure of CH3COOH as shown below is correct, but some of the bonds are shown incorrectly. Write the correct Lewis structure for acetic acid.
Using molecular orbital theory, compare the bond energy and magnetic character of 0+2 and O–2
Which hybrid orbitals are used by carbon atoms in the following molecules?
(a) CH3-CH3 (b) CH3-CH = CH2 (c) CH3-CH2-OH (d) CH3-CHO (e) CH3COOH.
Account for the following:
(i) Water is a liquid while H2S is a gas
(ii) NH3 has higher boiling point than PH3.
Arrange the following bonds ‘in order of increasing ionic character giving reason.
N-H, F-H, C-H and O-H
Name the two conditions which must be satisfied for hydrogen bonding to take place in a molecule.
(a) How many a and n bonds are present in
(b) Why Hf is more stable than H2?
(c) Why is B2 molecule paramagnetic?
Explain the diamagnetic behaviour of P2 molecule on the basis of molecular orbital theory.
Predict the shapes of the following molecules on the basis of hybridization. BC13, ch4, co2, nh3
3PO3 can be represented by structures 1 and 2 shown below. Can these two structures be taken as the canonical forms of the resonance hybrid representing H3PO3? If not, give reasons for the same.
What is meant by hybridisation of atomic orbitals? Describe the shapes of sp, sp2, sp3 hybrid orbitals.
Draw diagrams showing the formation of a double bond and a triple bond between carbon atoms in C2 H4 and C2 H2 molecules.
Explain the non linear shape of H2S and non planar shape of PCl3 using valence shell electron pair repulsion theory.
Use Lewis symbols to show electron transfer between the following atoms to form cations and anions (a) K and S (b) Ca and O (c) Al and N.
Define Lattice energy. How is Lattice energy influenced by (i) Charge on the ions (ii) Size of the ions?
Assertion (A): Though the central atom of both NH3 and H20 molecules are sp3 hybridised, yet H – N – H bond angle is greater than that of H – O – H.
Reason (R): This is because nitrogen atom has one lone pair and oxygen atom has two lone pairs.
(a) A and R both are correct, and R is the correct explanation of A.
(b) A and R both are correct, but R is not the correct explanation of A.
(c) A is true but R is false.
(d) A and R both are false.
Although geometries of NH3 and H20 molecules are distorted tetrahedral, bond angle in water is less than that of ammonia. Discuss.
Apart from tetrahedral geometry, another possible geometry for CH4 is square planar with the four H atoms at the comers of the square and the C atoms at its centre. Explain why CH4 is not square planar?